Ultrasonic emulsification of oil and water was carried out and the effect of irradiation time, irradiation power and physicochemical properties of oil on the dispersed phase volume and dispersed phase droplet size has been studied. The increase in the irradiation time increases the dispersed phase volume while decreases the dispersed phase droplets size. With an increase in the ultrasonic irradiation power, there is an increase in the fraction of volume of the dispersed phase while the droplet size of the dispersed phase decreases. The fractional volume of the dispersed phase increases for the case of groundnut oil-water system while it is low for paraffin (heavy) oil-water system. The droplet size of soyabean oil dispersed in water is found to be small while that of paraffin (heavy) oil is found to be large. These variations could be explained on the basis of varying physicochemical properties of the system, i.e., viscosity of oil and the interfacial tension. During the ultrasonic emulsification, coalescence phenomenon which is only marginal, has been observed, which can be attributed to the collision of small droplets when the droplet concentration increases beyond a certain number and the acoustic streaming strength increases.

Curcumin, a dietary phytochemical, has been extracted from rhizomes of Curcuma amada using ultrasound assisted extraction (UAE) and the results compared with the conventional extraction approach to establish the process intensification benefits. The effect of operating parameters such as type of solvent, extraction time, extraction temperature, solid to solvent ratio, particle size and ultrasonic power on the extraction yield have been investigated in details for the approach UAE. The maximum extraction yield as 72% was obtained in 1h under optimized conditions of 35°C temperature, solid to solvent ratio of 1:25, particle size of 0.09mm, ultrasonic power of 250W and ultrasound frequency of 22kHz with ethanol as the solvent. The obtained yield was significantly higher as compared to the batch extraction where only about 62% yield was achieved in 8h of treatment. Peleg's model was used to describe the kinetics of UAE and the model showed a good agreement with the experimental results. Overall, ultrasound has been established to be a green process for extraction of curcumin with benefits of reduction in time as compared to batch extraction and the operating temperature as compared to Soxhlet extraction.

Present investigation explores the use of pineapple peel, a food industry waste, for acetone-butanol-ethanol (ABE) production using Clostridium acetobutylicum B 527. Proximate analysis of pineapple peel shows that it contains 35% cellulose, 19% hemicellulose, and 16% lignin on dry basis. Drying experiments on pineapple peel waste were carried out in the temperature range of 60-120°C and experimental drying data was modeled using moisture diffusion control model to study its effect on ABE production. The production of ABE was further accomplished via acid hydrolysis, detoxification, and fermentation process. Maximum total sugar release obtained by using acid hydrolysis was 97g/L with 95-97% and 10-50% removal of phenolics and acetic acid, respectively during detoxification process. The maximum ABE titer obtained was 5.23g/L with 55.6% substrate consumption when samples dried at 120°C were used as a substrate (after detoxification).

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In the present study, press mud a sugar industry waste was explored for biobutanol production to strengthen agricultural economy. The fermentative production of biobutanol was investigated via series of steps viz. characterization, drying, acid hydrolysis, detoxification, and fermentation. Press mud contains adequate amount of cellulose (22.3%) and hemicellulose (21.67%) on dry basis and hence it can be utilized for further acetone-butanol-ethanol (ABE) production. Drying experiments were conducted in the temperature range of 60-120 °C to circumvent microbial spoilage and enhance storability of press mud. Furthermore, acidic pretreatment variables viz. sulfuric acid concentration, solid to liquid ratio, and time were optimized using response surface methodology. The corresponding values were found to be 1.5% (v/v), 1:5 g/mL, and 15 min, respectively. In addition, the detoxification studies were also conducted using activated charcoal that removed almost 93-97% phenolics and around 98% furans, which were toxic to microorganism during fermentation. Finally, the batch fermentation of detoxified press mud slurry (sample dried at 100 °C and pretreated) using Clostridium acetobutylicum NRRL B-527 resulted in higher butanol production of 4.43 g/L with total ABE of 6.69 g/L.

Biorefinery sector has become a serious dispute for cleaner and sustainable development in recent years. In the present study, pretreatment of pineapple peel waste was carried out in high pressure reactor using various pretreatment-enhancers. The type and concentration effect of each enhancer on hemicellulose solubilization was systematically investigated. The binary acid (phenol + sulfuric acid) at 180 °C was found to be superior amongst other studied enhancers, giving 81.17% (w/v) hemicellulose solubilization in liquid-fraction under optimized conditions. Solid residue thus obtained was subjected to enzymatic hydrolysis that resulted into 24.50% (w/v) cellulose breakdown. Treated solid residue was further characterized by scanning electron microscopy and Fourier transform infrared spectroscopy to elucidate structural changes. The pooled fractions (acid treated and enzymatically hydrolyzed) were fermented using Clostridium acetobutylicum NRRL B 527 which resulted in butanol production of 5.18 g/L with yield of 0.13 g butanol/g sugar consumed. Therefore, pretreatment of pineapple peel waste evaluated in this study can be considered as milestone in utilization of low cost feedstock, for bioenergy production.

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Introduction: Filler size affects how the material is coated and finished, while filler stacking affects how strong the material is, how flexible it is, how resistant it is to wear, and how much it shrinks when it polymerizes. The purpose of this research was to compare micro-hybrid, nano-composite, and bulk-fill composites with respect to their compressive strength, diametric tensile strength, and flexural strength. Materials and methods: To organize the samples according to International Organization for Standardization (ISO) 4049 and American Dental Association (ADA) detail number 27, we used a custom-made Teflon mold. A total of 45 samples were used, with 15 samples in each group. The sample was mounted on a state-of-the-art general testing machine to determine its compressive strength and polar rigidity. The 3-point bowing test was used to determine flexural strength. A one-way analysis of variance (ANOVA) was used for quantitative analysis, followed by a post hoc test with a significance level of P < 0.05. Results: The Tetric N Ceram Bulk Fill, the Filtek Z350 XT nanocomposite, and the T-Econom micro-hybrid composite all had different levels of flexural and compressive strength. This difference was statistically significant. Nanocomposites have superior compressive and flexural strengths to their counterparts analyzed in the present study. Conclusion: Nano-composite combines the properties of being strong and looking good. It can be used in both front and back restorations that need to be strong enough to withstand the forces of chewing.