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The tensile stress–strain behavior of Nafion 117 and sulfonated poly(arylene ether sulfone) copolymer (BPSH35) membranes were explored with respect to the effects of the strain rate, counterion type, molecular weight, and presence of inorganic fillers. The yielding properties of the two films were most affected by the change in the strain rate. The stress–strain curves of Nafion films in acid and salt forms exhibited larger deviations at strains above the yield strain. As the molecular weight of the BPSH35 samples increased, the elongation at break improved significantly. Enhanced mechanical properties were observed for the composite membrane of BPSH35 and zirconium phenylphosphonate (2% w/w) in comparison with its matrix BPSH35 film. The stress‐relaxation behavior of Nafion and BPSH35 membranes was measured at different strain levels and different strain rates. Master curves were constructed in terms of plots of the stress‐relaxation modulus and time on a double‐logarithm scale. A three‐dimensional bundle‐cluster model was proposed to interpret these observations, combining the concepts of elongated polymer aggregates, proton‐conduction channels, and states of water. The rationale focused on the polymer bundle rotation/interphase chain readjustment before yielding and polymer aggregate disentanglements and reorientation after yielding. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1453–1465, 2006

Abstract. The High Efficiency and Resolution Multi Element Spectrograph, HERMES, is a facility-class optical spectrograph for the Anglo-Australian Telescope (AAT). It is designed primarily for Galactic Archaeology, the first major attempt to create a detailed understanding of galaxy formation and evolution by studying the history of our own galaxy, the Milky Way. The goal of the GALAH survey is to reconstruct the mass assembly history of the Milky Way through a detailed chemical abundance study of one million stars. The spectrograph is based at the AAT and is fed by the existing 2dF robotic fiber positioning system. The spectrograph uses volume phase holographic gratings to achieve a spectral resolving power of 28,000 in standard mode and also provides a high-resolution mode ranging between 40,000 and 50,000 using a slit mask. The GALAH survey requires an SNR greater than 100 for a star brightness of V ¼ 14 in an exposure time of one hour. The total spectral coverage of the four channels is about 100 nm between 370 and 1000 nm for up to 392 simultaneous targets within the 2-degree field of view. HERMES has been commissioned over three runs, during bright time in October, November, and December 2013, in parallel with the beginning of the GALAH pilot survey, which started in November 2013. We present the first-light results from the commissioning run and the beginning of the GALAH survey, including performance results such as throughput and resolution, as well as instrument reliability. © The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.

Aluminum alloys are increasingly being used in a broad spectrum of load-bearing applications such as lightweight structures, light rail, bridge decks, marine crafts, and offshore platforms. A major concern in the design of land-based and marine aluminum structures is fire safety, at least in part due to mechanical property reduction at temperatures significantly lower than that for steel. A substantial concern also exists regarding the integrity and stability of an aluminum structure following a fire; however, little research has been reported on this topic. This paper provides a broad overview of the mechanical behavior of aluminum alloys both during and following fire. The two aluminum alloys discussed in this work, 5083-H116 and 6061-T651, were selected due to their prevalence as lightweight structural alloys and their differing strengthening mechanisms (5083strain hardened, 6061precipitation hardened). The high temperature quasi-static mechanical and creep behavior are discussed. A creep model is presented to predict the secondary and tertiary creep strains followed by creep rupture. The residual mechanical behavior following fire (with and without applied stress) is elucidated in terms of the governing kinetically-dependent microstructural mechanisms. A review is provided on modeling techniques for residual mechanical behavior following fire including empirical relations, physically-based constitutive models, and finite element implementations. The principal objective is to provide a comprehensive description of select aluminum alloys, 5083-H116 and 6061-T651, to aid design and analysis of aluminum structures during and after fire.

The near-infrared is an important part of the spectrum in astronomy, especially in cosmology because the light from objects in the early universe is redshifted to these wavelengths. However, deep near-infrared observations are extremely difficult to make from ground-based telescopes due to the bright background from the atmosphere. Nearly all of this background comes from the bright and narrow emission lines of atmospheric hydroxyl (OH) molecules. The atmospheric background cannot be easily removed from data because the brightness fluctuates unpredictably on short timescales. The sensitivity of ground-based optical astronomy far exceeds that of near-infrared astronomy because of this long-standing problem. GNOSIS is a prototype astrophotonic instrument that utilizes "OH suppression fibers" consisting of fiber Bragg gratings and photonic lanterns to suppress the 103 brightest atmospheric emission doublets between 1.47 and 1.7 µm. GNOSIS was commissioned at the 3.9 m Anglo-Australian Telescope with the IRIS2 spectrograph to demonstrate the potential of OH suppression fibers, but may be potentially used with any telescope and spectrograph combination. Unlike previous atmospheric suppression techniques GNOSIS suppresses the lines before dispersion and in a manner that depends purely on wavelength. We present the instrument design and report the results of laboratory and on-sky tests from commissioning. While these tests demonstrated high throughput (≈ 60%) and excellent suppression of the skylines by the OH suppression fibers, surprisingly GNOSIS produced no significant reduction in the interline background and the sensitivity of GNOSIS+IRIS2 is about the same as IRIS2. It is unclear whether the lack of reduction in the interline background is due to physical sources or systematic errors as the observations are detector noise dominated. OH suppression fibers could potentially impact ground-based astronomy at the level of adaptive optics or greater. However, until a clear reduction in the interline background and the corresponding increasing in sensitivity is demonstrated optimized OH suppression fibers paired with a fiber-fed spectrograph will at least provide a real benefit at low resolving powers.