The 13C nmr spectra of 4 cis‐2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonanes, 11 cis‐2,4‐diaryl‐3‐azabicyclo[3.3.1]‐nonan‐9‐ones, 26 cis‐2,4‐diaryl‐3‐azabicyclo[3.3.1]‐nonan‐9‐ols or acetates thereof, 5 cis‐2,4‐diaryl‐3‐azabi‐cyclo[4.3.1]decan‐10‐ones or ‐10‐ols and 5 cis‐2,4‐diphenyl‐3‐aza‐7‐thiabicyclo[3.3.1]nonan‐9‐ones, ‐9‐ols or 9‐yl acetates have been recorded. Except for the 7‐thia compounds, which appear to exist mainly in the configuration and conformation with the nitrogen‐containing ring in the boat form, these compounds seem to exist overwhelmingly in chair‐chair conformations. The configuration of the 9‐ols and their acetates (syn or anti to the nitrogen‐containing ring) has been deduced from the spectra. In a number of cases, the structures assigned differ from those earlier postulated. Broadening of one set of aryl signals (probably those due to the ortho carbons) in the case of N‐methyl (but not N‐H) compounds without ortho substituents is ascribed to restricted phenyl rotation.
Subject librarians are uniquely poised to facilitate conversations and assistance
about scholarly communication topics to faculty and students -- helping make the
connections between scholarly communication and discipline-specific research. The
University of Central Florida (UCF) Libraries offers a unique intersection between
scholarly communication and subject librarians by implementing a robust subject
librarian model that includes activities related to scholarly communication and
partnering with UCF’s Office of Scholarly Communication to provide support on a variety
of topics to the campus community. In particular, this model has been particularly
effective with STEM disciplines. The subject librarians in these respective disciplines
have actively partnered with the Office of Scholarly Communication to provide a series
of workshops targeted to STEM faculty on topics such as predatory publishing. These
conversations have prompted invitations to speak at college and department meetings and
to provide additional assistance and support on these scholarly communication topics. It
has also led to a research project conducted by the science, engineering and computer
science librarians and the Scholarly Communication Librarian on the open access
publishing practices and trends of UCF STEM faculty to help better inform conversations
and research support to these faculty. This article will explore the various ways in
which this unique model aids UCF Libraries in providing scholarly communication support
to faculty and students in an effective way and will share specific strategies and
examples that readers can practically implement at their respective
institutions.
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