Different vegetable crops grown on heavy metal contaminated soil showed marked difference in metal accumulation, their uptake and distribution pattern. Crop species also showed remarkable difference in metal concentration of various plant parts. Based on metal accumulation in edible parts and whole plants, root vegetables namely, radish and carrot registered lower accumulation of almost all heavy metals except Zn in radish root. However, leafy vegetables namely, spinach, amaranthus, mustard and fenugreek recorded higher accumulation of both essential and non-essential heavy metals, except Cd and Ni which showed less accumulation in fenugreek. Potato and onion showed lower accumulation of Zn and Cu and higher accumulation of Cd and Ni. Cauliflower and cabbage, however, showed greater accumulation of Pb and Ni, but less accumulation of Cu and Cd. Among fruit type vegetables, pea, soybean and cluster bean showed greater accumulation of Pb and Ni and very less accumulation of Cd. Among different vegetables cauliflower and cabbage recorded highest uptake of Zn, Pb and Ni, while mustard showed higher uptake of Zn and Cd. In general the uptake of Cd was lowest in almost all the crops except mustard. Generally the root and leafy vegetables namely. radish, carrot, spinach, amaranthus, mustard, cauliflower and cabbage showed higher distribution of metals to the edible parts, whereas fruit types vegetables specially tomato and brinjal exhibited least transport of metals to fruits except leguminous fruit vegetables pea and soybean. Leafy vegetables namely, spinach, amaranthus and mustard seemed to be unsafe and not suitable for cultivation on heavy metal contaminated soil. Most of the fruit type vegetables could be suggested for cultivation on Cd contained soil but not for Ni and Pb contained soil.
Kota City is a prominent industrial and educational town of Rajasthan state, India. Mega industrial projects of cement, fertilizers, power plant, oil seed processing units are located nearby the city. The groundwater of study area is used in domestic as well as in industrial activities. It is worthwhile to know the water quality status and its effect on entity, which is exposed in practical use. A comprehensive assessment of water quality parameters in groundwater samples drawn from 24 different locations, 6 sites from each direction at outer skirts of Kota City of Rajasthan, India, in four seasons of years 2006 to 2008 was carried out. To find out the suitability and stability of water, various indices available to assess the scale formation and corrosivity was used. The Langelier saturation index (LSI) and Ryznar saturation index (RSI) were calculated and discussed with respect to saturation level.
The Corrosion inhibition of mild steel in 1 M HCl solution with aqueous extract of Ziziphus Jujuba stem and Ziziphus Jujuba fruits is studied by weight loss method at 303-333K temperatures. It is found that inhibition efficiency rise with increase in concentration of extract and decreased with rise in temperature. Maximum 78.05% inhibition efficiency was observed at 303 K and 8% (v/v) concentration of Ziziphus Jujuba stem. While maximum 68.60% inhibition efficiency was observed at 303 K and 8% (v/v) concentration of Ziziphus Jujuba fruits. Value observed for Activation energy, Gibbs free energy and variation in I.E. with temp Suggest physisorption. Adsorption of extract at mild steel surface follows Langmuir adsorption isotherm. Negative values of Gibbs energy reveals the spontaneity of inhibition process in extracts at studied temperatures.
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