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Thin films of thermochromic VO2, V1−xWxO2 and V1−x−yWxTiyO2 (x=0.014, and y=0.12) were synthesized onto quartz substrates using a reactive pulsed laser deposition technique. The films were then characterized by x-ray diffraction and x-ray photoelectron spectroscopy. The W and Ti dopant effects on the semiconductor-to-metal phase transition of VO2 were investigated by measuring the temperature dependence of their electrical resistivity and their infrared transmittance. Remarkably strong effects of Ti–W codoping were observed on both the optical and electrical properties of V1−x−yWxTiyO2 films. The IR transmittance was improved, while the transition temperature could be varied from 36°C for W-doped VO2 film to 60°C for Ti–W codoped VO2 film. In addition, at room temperature, a higher temperature coefficient of resistance of 5.12%∕°C is achieved. Finally, both optical and electrical hysteresis are completely suppressed by Ti–W codoping the VO2 films.

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The parameters of reactive pulsed laser deposition were successfully optimized for fabrication of vanadium dioxide thin films. It is observed that the O2 concentration in Ar gas and the total deposition pressure are critical in stabilizing the single VO2 phase. Thermochromic VO2 and V1−xWxO2 (x=0.014) thin films were synthesized on various substrates (silicon, quartz, and sapphire) at 5% of O2/Ar ratio gas and total pressure of 90 mTorr. The structural properties of the deposited films were analyzed by x-ray diffraction, while their semiconductor-to-metal phase transitions were studied by electrical resistivity using the four-point technique and infrared transmittance from room temperature up to 100 °C. The observed transition temperature was about 36 °C for W-doped VO2 compared to 68 °C for VO2 films. This transition temperature was then lowered by about 22.85 °C per 1 at. % of W added. The temperature coefficient of resistance was about 1.78%/°C for VO2 and about 1.90%/°C for W-doped VO2. Using the pump-probe experiment, the application of these thermochromic films as optical switches was demonstrated at the wavelength of 1.55 μm. The transmission switching was about 25 dB for VO2 and 28 dB for W-doped VO2. In addition, application of VO2 on optical fiber components was demonstrated by direct VO2 coating on the end faces of cleaved single mode optical fibers and optical fiber connectors.

[1] The validity of recent identification of various hydrated minerals (kieserite, gypsum, hexahydrite, nontronite, chamosite, and montmorillonite) on Mars was assessed by exposing these minerals to simulated Martian surface conditions of atmospheric composition and pressure, temperature, and ultraviolet light irradiation. When exposed to such conditions the hydrated minerals exhibit in general, greater losses of interlayer H 2 O than structural OH. Minerals such as gypsum that contain structural H 2 O are more resistant to H 2 O loss than phyllosilicates. The partial loss of OH in some of the phyllosilicates is not accompanied by a measurable and systematic change in the wavelength position or intensity of metal-OH absorption bands. The characteristic absorption features that allow for identification of these minerals on Mars may be reduced in intensity, but are nevertheless largely preserved.

Fiber Bragg gratings (FBGs) are key elements in modern telecommunication and sensing applications. In optical communication, with the advancement of the Erbium doped fiber amplifier (EDFA), there is a great demand for devices with wavelength tunability over the Erbium gain bandwidth (in particular, for wavelength division multiplexing (WDM) networks). The center wavelength of a FBG can be shifted by means of change of temperature, pressure or mechanical axial strain. The axial strain approach is the best method among all other techniques because it allows relatively large wavelength shifts with high speed. Axial strain of up to 4% will be required to cover the whole EDFA region (more than 40 nm of central wavelength shift). The formation of Bragg grating results in significant reduction in mechanical strength of optical fibers especially in tension. As a result, axial strain of only about 1% can be achieved by mechanical stretching of FBGs. In order to achieve the remaining 3% strain compression of FBGs has to be applied.In this thesis, the design and analysis of a novel device for achieving central wavelength shift are presented. In particular, the device has achieved, for a fiber with Further, using the piezoelectric transducer (PZT) actuator as a driver, tuning speed of around 1.5nm/ms was achieved.-iii - ACKNOWLEDGMENTSUpon the completion of this thesis, I would like to express my sincere gratitude and appreciation to my supervisors Professor Chris W.

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