Advances in microelectronics have led to the development of on-chip intelligent microsystems that can digitalize the physical world, offering functions of sensing, data communication, and intelligent response to stimuli. Either mismatched form factors or limited energy density of available batteries compromises their integration. We report a microimprint fabrication for on-chip Zn−air microbatteries, which bypasses the complication of the catalyst incorporation on the chip at a target position. The on-chip integration of a bifunctional catalyst covalent organic framework with cobalt catalytic unitsenables the onchip Zn−air microbattery to outperform the Zn−air primary cell, showing 3 times more volumetric energy density. It is wirelessly chargeable, and its lifetime capacity is around twice longer than that for commercially available on-chip lithium ion microbatteries. The on-chip Zn−air microbattery can drive various electronic systems. Our approach bridges a long-standing gulf between advanced materials synthesis and their on-chip integration and paves the way toward high-performance on-chip Zn−air batteries.
The monosaccharides
glucose, fructose, and xylose were subjected
to hydrothermal carbonization in aqueous solution at temperatures
of 180, 220, and 250 °C for different operating times (30 min
to 16 h). Here, 68% to 78% of the organic carbon was converted into
hydrochar at 220 °C with glucose and fructose as feedstock, whereas
hydrothermal treatment of xylose did not result in significant hydrochar
formation under these conditions. The main topic of this contribution
was the identification of stable organic products in the process water
in the molecular mass range between 120 and 300 Da by means of GC-MS
analysis using several derivatization agents. Special attention was
paid to polar OH- and COOH-functionalized compounds. The overwhelming
majority of identified organic compounds had cyclic structures of
which a prominent group included hydroxylated benzofurans. However,
the combined yield of products, which might be potential substrates
for liquid biofuels, turned out very low.
Process
water reuse was exercised in the hydrothermal carbonization
(HTC) of paper at 200 °C for 16 h, four times. Results showed
that hydrochar mass yields increased significantly in the first recirculation
step but only slightly in further steps. At the same time, solid carbon
content did not increase, and a constant organic carbon distribution
between the three product streams, hydrochar, process water (PW),
and gas phase, was observed over all recycling steps. Dissolved organic
carbon content (DOC) and chemical oxygen demand (COD) of the PWs increased,
as well as total acids content, among those specifically lactic, acetic,
formic, and propionic acid. Surprisingly, the aerobic biodegradability
of the PWs decreased as indicated by lower biochemical to chemical
oxygen demand (BOD/COD) ratios in reused process waters. Subsequent
methanogenesis of the PW revealed that a high amount of biogas was
produced; however, no increase was seen with each recirculation step.
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