Synthesis of water soluble MoS2 quantum dots from the monolayer nanosheets of MoS2, using thioglycolic acid (TGA) was reported in this study. TGA molecules not only exfoliated the bulk of MoS2, but also modified the hydrophobic surface of MoS2 with hydrophilic carboxylic acid groups.
Raman enhancement on nonmetallic flat two-dimensional (2D) nanomaterial surfaces has attracted a great deal of attention since the discovery of graphene-enhanced Raman scattering.
Despite their frequent usages as contrast agents for in vivo MRI imaging, paramagnetic molecules continue to suffer from low resolution, physicochemical instability, and high toxicity. Herein, we present a molybdenum disulfide and gadolinium complex, as an alternative core-shell magnetic nanomaterial that exhibits enhanced paramagnetic property; 4.5-times longer water proton spin-lattice relaxation time (T1) when compared to commercial gadolinium contrast agents; as well as lowered toxicity, extended blood circulation time, increased stability, and desirable excretion characteristic. Transmission electron microscopy (TEM) revealed smooth core-shell nanoparticles 100 nm in size with a shell width of approximately 10 nm. These findings suggest that the synthesized nanomaterial possesses high potential as a positive contrast agent for the enhancement of MRI imaging.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.