Hydrogen technologies have experienced cycles of excessive expectations followed by disillusion. Nonetheless, a growing body of evidence suggests these technologies form an attractive option for the deep decarbonisation of global energy systems, and that recent improvements in their cost and performance point towards economic viability as well. This paper is a comprehensive review of the potential role that hydrogen could play in the provision of electricity, heat, industry, transport and energy storage in a low-carbon energy system, and an assessment of the status of hydrogen in being able to fulfil that potential. The picture that emerges is one of qualified promise: hydrogen is well established in certain niches such as forklift trucks, while mainstream applications are now forthcoming.Hydrogen vehicles are available commercially in several countries, and 225 000 fuel cell home heating systems have been sold. This represents a step change from the situation of only five years ago. This review shows that challenges around cost and performance remain, and considerable improvements are still required for hydrogen to become truly competitive. But such competitiveness in the medium-term future no longer seems an unrealistic prospect, which fully justifies the growing interest and policy support for these technologies around the world. Broader contextHydrogen and fuel cells have arguably suffered a 'lost decade' after high expectations in the 2000s failed to materialise. Three factors are enabling the sector to regain momentum. Firstly, improvements in technology and manufacturing mean that systems which cost $60 000 in 2005 are now cost $10 000. Secondly, commercial products are becoming widely available, and significant uptake is occurring in specific sectors such as Japanese microgeneration and US forklift trucks. Thirdly, a strengthened global resolve to mitigate climate change is coupled with increasing realisation that clean power alone is insufficient, due to the complexity of decarbonising heat and transport. This paper provides a comprehensive state-of-the-art update on hydrogen and fuel cells across transport, heat, industry, electricity generation and storage, spanning the technologies, economics, infrastructure requirements and government policies. It defines the many roles that these technologies can play in the near future, as a flexible and versatile complement to electricity, and in offering end-users more choice over how to decarbonise the energy services they rely on. While there are strong grounds for believing that hydrogen and fuel cells can experience a cost and performance trajectory similar to those of solar PV and batteries, several challenges must still be overcome for hydrogen and fuel cells to finally live up to their potential.
Replacing fossil fuels with energy sources and carriers that are sustainable, environmentally benign, and affordable is amongst the most pressing challenges for future socio-economic development.
(a, b,*) , James Brierley (c) , Chester Lewis (d) , Line Skatvedt (c) , Jamie Speirs (a, e) , Adam Hawkes (a, b) , Iain Staffell (c)
The levelized cost of carbon mitigation and proportional decarbonisation fraction ranges of hydrogen production technologies relative to steam methane reforming.
Natural gas is typically considered to be the cleaner-burning fossil fuel that could play an important role within a restricted carbon budget. Whilst natural gas emits less CO2 when burned than other fossil fuels, its main constituent is methane, which has a much stronger climate forcing impact than CO2 in the short-term. Estimates of methane emissions in the natural gas supply chain have been the subject of much controversy, due to uncertainties associated with estimation methods, data quality and assumptions used. This paper presents a comprehensive compilation of estimated CO2 and methane emissions across the global natural gas supply chain, with the aim of providing a balanced insight for academia, industry and policy makers by summarising the reported data, locating the areas of major uncertainty and identifying where further work is needed to reduce or remove this uncertainty. Overall, the range of documented estimates of methane emissions across the supply chain is vast amongst an aggregation of different geological formations, technologies, plant age, gas composition and regional regulation, not to mention differences in estimation methods. Estimates of combined methane and CO2 emissions ranged from 2 -42 g CO2 eq./ MJ HHV, whilst methane-only emissions ranged from 0.2% -10% of produced methane. The methane emissions at the extraction stage are the most contentious issue, with limited data available but potentially large impacts associated with well completions for unconventional gas, liquids unloading and also from the transmission stage. From the range of literature estimates, a constrained range of emissions was estimated that reflects the most recent and reliable estimates: total supply chain GHG emissions were estimated to be between 3.6 and 42.4 g CO2 eq./ MJ HHV, with a central estimate of 10.5. The presence of 'super emitters', a small number of facilities or equipment that cause extremely high emissions, is found across all supply chain stages creating a highly skewed emissions distribution. However, various new technologies, mitigation and maintenance approaches, and legislation are driving significant reductions in methane leakage across the natural gas supply chain.
Methane is a more potent greenhouse gas (GHG) than CO2, but it has a shorter atmospheric lifespan, thus its relative climate impact reduces significantly over time. Different GHGs are often conflated into a single metric to compare technologies and supply chains, such as the global warming potential (GWP). However, the use of GWP is criticised, regarding: (1) the need to select a timeframe; (2) its physical basis on radiative forcing; and (3) the fact that it measures the average forcing of a pulse over time rather than a sustained emission at a specific end-point in time. Many alternative metrics have been proposed which tackle different aspects of these limitations and this paper assesses them by their key attributes and limitations, with respect to methane emissions. A case study application of various metrics is produced and recommendations are made for the use of climate metrics for different categories of applications. Across metrics, CO2 equivalences for methane range from 4-199 gCO2eq./gCH4, although most estimates fall between 20 and 80 gCO2eq./gCH4. Therefore the selection of metric and time horizon for technology evaluations is likely to change the rank order of preference, as demonstrated herein with the use of natural gas as a shipping fuel versus alternatives. It is not advisable or conservative to use only a short time horizon, e.g. 20 years, which disregards the long-term impacts of CO2 emissions and is thus detrimental to achieving eventual climate stabilisation. Recommendations are made for the use of metrics in 3 categories of applications. Short-term emissions estimates of facilities or regions should be transparent and use a single metric and include the separated contribution from each GHG. Multi-year technology assessments should use both short and long term static metrics (e.g. GWP) to test robustness of results. Longer term energy assessments or decarbonisation pathways must use both short and long-term metrics and where this has a large impact on results, climate models should be incorporated. Dynamic metrics offer insight into the timing of emissions, but may be of only marginal benefit given uncertainties in methodological assumptions.
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