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• Retrievals of far infrared surface emissivity are reported for the first time, exploiting aircraft observations taken over Greenland. • The retrieved emissivity reaches values as low as 0.89 over the range 360-535 cm-1 , where the associated uncertainties are smallest. • Simulations of the surface emissivity are unable to simultaneously match retrievals in the far and mid infrared.

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Research funded by the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) program has led to significant improvements in longwave radiative transfer modeling over the last decade. These improvements, which have generally come in small incremental changes, were made primarily in the water vapor self- and foreign-broadened continuum and the water vapor absorption line parameters. These changes, when taken as a whole, result in up to a 6 W m−2 improvement in the modeled clear-sky downwelling longwave radiative flux at the surface and significantly better agreement with spectral observations. This paper provides an overview of the history of ARM with regard to clear-sky longwave radiative transfer, and analyzes remaining related uncertainties in the ARM state-of-the-art Line-by-Line Radiative Transfer Model (LBLRTM). A quality measurement experiment (QME) for the downwelling infrared radiance at the ARM Southern Great Plains site has been ongoing since 1994. This experiment has three objectives: 1) to validate and improve the absorption models and spectral line parameters used in line-by-line radiative transfer models, 2) to assess the ability to define the atmospheric state, and 3) to assess the quality of the radiance observations that serve as ground truth for the model. Analysis of data from 1994 to 1997 made significant contributions to optimizing the QME, but is limited by small but significant uncertainties and deficiencies in the atmospheric state and radiance observations. This paper concentrates on the analysis of QME data from 1998 to 2001, wherein the data have been carefully selected to address the uncertainties in the 1994–97 dataset. Analysis of this newer dataset suggests that the representation of self-broadened water vapor continuum absorption is 3%–8% too strong in the 750–1000 cm−1 region. The dataset also provides information on the accuracy of the self- and foreign-broadened continuum absorption in the 1100–1300 cm−1 region. After accounting for these changes, remaining differences in modeled and observed downwelling clear-sky fluxes are less than 1.5 W m−2 over a wide range of atmospheric states.

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Coal fly ash (CFA) is a significant environmental pollutant that presents a respiratory hazard when airborne. Although previous studies have identified the mineral components of CFA, there is a paucity of information on the structural habits of these minerals. Samples from UK, Polish and Chinese power stations were studied to further our understanding of the factors that affect CFA geochemistry and mineralogy. ICP-MS, FE-SEM/EDX, XRD, and laser diffraction were used to study physicochemical characteristics. Analysis revealed important differences in the elemental compositions and particle size distributions of samples between sites. Microscopy of HF acid-etched CFA revealed the mullite present possesses a fibrous habit; fibres ranged in length between 1 and 10 μm. Respirable particles (<10 μm) were frequently observed to contain fibrous mullite. We propose that the biopersistence of these refractory fibres in the lung environment could be contributing towards chronic lung diseases seen in communities and individuals continually exposed to high levels of CFA.

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