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The effects of the block copolymer composition and the solvent selectivity on the micellar morphologies of poly(styrene- b-4-vinylpyridine)s (PS- b-P4VPs) and their functionalizations with gold were studied in 10 mg/mL solutions using small-angle X-ray scattering and transmission electron microscopy (TEM). The solvent selectivity for the PS block was controlled by toluene/tetrahydrofuran (THF) mixtures in which toluene and THF are selective for PS and nonselective, respectively. The micellar structure was strongly dependent on phi (wt % toluene in toluene/THF mixture) and the composition of the block copolymers. PS(12K)- b-P4VP(11.8K) (symmetric) showed spherical micelles in the entire range of phi except phi = 0 (THF, nonselective solvent). PS(3.3K)- b-P4VP(18.7K) (asymmetric, longer P4VP) showed multiple morphologies with transitions from spheres to cylinders and finally to vesicles with an increase in phi. PS(19.6K)- b-P4VP(5.1K) (asymmetric, longer PS) showed spherical micelles only at the narrow ranges of 90 wt %

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It is highly desired to synthesize low‐cost photocatalysts for the degradation of colored dyes to safeguard our environment for the future generations. Here, we report an extremely efficient and low‐cost synthesis of alkaline earth and transition‐metal ferrite photocatalysts (MgFe2O4, CaFe2O4, BaFe12O19, CuFe2O4, and ZnFe2O4) from their chloride salts and their applications for the degradation of methylene blue (MB) dye under UV–visible and direct sunlight irradiation. The as‐prepared photocatalysts displayed enhanced photoactivities under both conditions of irradiation. After calcination at 600°C, the photocatalytic degradation increased significantly, and 96 and 85% MB was removed with ZnFe2O4 under UV–visible and direct sunlight irradiation, respectively. Moreover, large amounts of hydroxyl free radicals were produced under both irradiation conditions, which participated in the degradation of MB. The enhanced photodegradation activities of these photocatalysts are attributed to their extended visible light absorption and low bandgaps. This work will provide a feasible route to the synthesis of efficient and low‐cost photocatalysts to utilize sunlight for environmental remediation.

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