Sources, pathways and reservoirs of microplastics, plastic particles smaller than 5mm, remain poorly documented in an urban context. While some studies pointed out wastewater treatment plants as a potential pathway of microplastics, none have focused on the atmospheric compartment. In this work, the atmospheric fallout of microplastics was investigated in two different urban and sub-urban sites. Microplastics were collected continuously with a stainless steel funnel. Samples were then filtered and observed with a stereomicroscope. Fibers accounted for almost all the microplastics collected. An atmospheric fallout between 2 and 355 particles/m(2)/day was highlighted. Registered fluxes were systematically higher at the urban than at the sub-urban site. Chemical characterization allowed to estimate at 29% the proportion of these fibers being all synthetic (made with petrochemicals), or a mixture of natural and synthetic material. Extrapolation using weight and volume estimates of the collected fibers, allowed a rough estimation showing that between 3 and 10 tons of fibers are deposited by atmospheric fallout at the scale of the Parisian agglomeration every year (2500 km(2)). These results could serve the scientific community working on the different sources of microplastic in both continental and marine environments.

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Abstract:The nonpoint source pollution problem can be controlled by implementing various best management practices (BMPs) in the watershed. However, before such practices are adopted, their effectiveness at various spatial and temporal scales must be evaluated. The objective of this research was to evaluate a suite of BMPs in a pasture-dominated watershed in their effectiveness at controlling nutrient losses. A total of 171 different BMP combinations incorporating grazing and pasture management, riparian and buffer zones, and poultry litter applications were evaluated for their effectiveness using the Soil and Water Assessment Tool (SWAT) model. The SWAT model was parameterized using detailed farm and watershed-scale data. The stochasticity in weather was captured by generating 250 various possible weather realizations for a 25-year period, using measured historical climate data for the watershed. Model results indicated that losses of both total nitrogen, mineral phosphorus, and total phosphorus increased with an increase in litter application rates. For the same application rates, greatest losses were predicted for fall application timings compared to spring and summer applications. Overgrazing resulted in greater nutrient losses compared to baseline conditions for all application rates, timings, and litter characteristics, indicating that overgrazing of pasture areas must be avoided if any improvement in the water quality is to be expected. Variability in weather conditions significantly affected BMP performance; under certain weather conditions, an increase in pollutant losses can be greater than reductions due to BMPs implemented in the watershed. Buffer strips and grazing management were two most important BMPs affecting the losses of total nitrogen and total phosphorus from the pasture areas.

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The generation of a coherent state, supporting a large photon number, with controlled orbital-angular-momentum L = ħl (of charge l per photon) presents both fundamental and technological challenges: we demonstrate a surface-emitting laser, based on III-V semiconductor technology with an integrated metasurface, generating vortex-like coherent state in the Laguerre-Gauss basis. We use a first order phase perturbation to lift orbital degeneracy of wavefunctions, by introducing a weak anisotropy called here “orbital birefringence”, based on a dielectric metasurface. The azimuthal symmetry breakdown and non-linear laser dynamics create “orbital gain dichroism” allowing selecting vortex handedness. This coherent photonic device was characterized and studied, experimentally and theoretically. It exhibits a low divergence (<1°) diffraction limited beam, emitting 49 mW output power in the near-IR at λ ≃ 1 μm, a charge l = ±1, … ±4 (>50 dB vortex purity), and single frequency operation in a stable low noise regime (0.1% rms). Such high performance laser opens the path to widespread new photonic applications.

The first large-scale network of tree-ring chronologies from the western Mediterranean (WM; 32°N-43°N, 10°W-17°E) is described and analyzed to identify the seasonal climatic signal in indices of annual ring width. Correlation and rotated empirical orthogonal function analyses are applied to 85 treering series and corresponding gridded climate data to assess the climate signal embedded in the network. Chronologies range in length from 80 to 1129 years. Monthly correlations and partial correlations show overall positive associations for Pinus halepensis (PIHA) and Cedrus atlantica (CDAT) with winter (December-February) and spring (March-May) precipitation across this network. In both seasons, the precipitation correlation with PIHA is stronger, while CDAT chronologies tend to be longer. A combination of positive correlations between growth and winter-summer precipitation and negative partial correlations with growing season temperatures suggests that chronologies in at least part of the network reflect soil moisture and the integrated effects of precipitation and evapotranspiration signal. The range of climate response observed across this network reflects a combination of both species and geographic influences. Western Moroccan chronologies have the strongest association with the North Atlantic Oscillation.

This paper compares the performance of three geostatistical algorithms, which integrate elevation as an auxiliary variable: kriging with external drift (KED

We revisit and improve the optical heterodyne technique for the measurement of the laser coherence, by digital acquisition of the beat-note and numerical analysis of the resulting signal. Our main result is that with the same experimental setup we reach the very "short-time linewidth" with the highest accuracy as well as the frequency noise spectrum.