We report results from a plasma source; a diffuse coplanar surface discharge (DCSD), which is capable of generating macroscopically uniform thin layers of diffuse plasmas in air and other reactive gases at atmospheric pressure. DCSD is a type of dielectric barrier discharge generated on the surface of a dielectric barrier with embedded electrodes, which appears to be advantageous to surface treatment and deposition processes. Preliminary results on hydrophilization of polypropylene nonwoven fabric are also presented.
Monolithic two-terminal
(2T) perovskite/CuInSe
2
(CIS)
tandem solar cells (TSCs) combine the promise of an efficient tandem
photovoltaic (PV) technology with the simplicity of an all-thin-film
device architecture that is compatible with flexible and lightweight
PV. In this work, we present the first-ever 2T perovskite/CIS TSC
with a power conversion efficiency (PCE) approaching 25% (23.5% certified,
area 0.5 cm
2
). The relatively planar surface profile and
narrow band gap (∼1.03 eV) of our CIS bottom cell allow us
to exploit the optoelectronic properties and photostability of a low-Br-containing
perovskite top cell as revealed by advanced characterization techniques.
Current matching was attained by proper tuning of the thickness and
bandgap of the perovskite, along with the optimization of an antireflective
coating for improved light in-coupling. Our study sets the baseline
for fabricating efficient perovskite/CIS TSCs, paving the way for
future developments that might push the efficiencies to over 30%.
A simplified Cu(In, Ga)Se2 (CIGS) solar cell structure based on a 500 nm thin CIGS layer is presented. The absorber layers are grown with a single-stage co-evaporation process and various KF post deposition treatments (KF-PDT) are performed. The KF-PDT leads to an efficiency increase from 7% to 12%. For all cells an increase in open circuit voltage (Voc) and fill factor is measured, which is attributed to an improved pn junction. By changing the annealing conditions an additional Voc increase is measured. This increase is attributed to the reduction of light induced defects at the CIGS/CdS interface in addition to the improved pn junction. A reduction of defects is confirmed by reduced sub band gap emission in the photoluminescence spectra, an increased decay time and increased quasi fermi level splitting. With SCAPS the results are simulated and it is concluded that after KF-PDT the Voc is limited to 640 mV due to recombination at the back contact. A higher Voc can then only be achieved by applying a passivation layer at the back. There are no indications that the single-stage process is limiting the efficiency revealing the potential of the proposed simplified CIGS structure and the importance of interfaces for ultrathin CIGS solar cells.
Undoped zinc oxide (ZnO) films have been grown on a moving glass substrate by plasma-enhanced chemical vapor deposition at atmospheric pressure. High deposition rates of~7 nm/s are achieved at low temperature (200°C) for a substrate speed from 20 to 60 mm/min. ZnO films are highly transparent in the visible range (90%). By a short (~minute) post-deposition exposure to near-ultraviolet light, a very low resistivity value of 1.6·10 À3 Ω cm for undoped ZnO is achieved, which is independent on the film thickness in the range from 180 to 1200 nm. The photo-enhanced conductivity is stable in time at room temperature when ZnO is coated by an Al 2 O 3 barrier film, deposited by the industrially scalable spatial atomic layer deposition technique. ZnO and Al 2 O 3 films have been used as front electrode and barrier, respectively, in Cu(In,Ga)Se2 (CIGS) solar cells. An average efficiency of 15.4 ± 0.2% (15 cells) is obtained that is similar to the efficiency of CIGS reference cells in which sputtered ZnO:Al is used as electrode.
Thin layers of atmospheric-pressure non-equilibrium plasma can be generated by pulse surface corona discharges and surface barrier discharges developing on the treated surfaces or brought into a close contact with the treated surfaces. Plasma sources based on these discharge types have the potential of meeting the basic on-line production requirements in the industry and can be useful for a wide range of surface treatments and deposition processes including continuous treatment of textiles. Comparing with atmospheric pressure glow discharge sources, the potential advantages of these plasma sources include their simplicity, robustness, and capability to process in a wide range of working gases.
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