Self‐cross‐linkable ferrocenyl‐containing polymethylhydrosiloxanes were synthesized. Karstedt's catalyst and cis‐[PtCl2(BnCN)2] were examined as cross‐linking catalysts at room temperature for the reaction between Si–H groups of the ferrocenyl‐containing polymethylhydrosiloxanes. Cis‐[PtCl2(BnCN)2] is an effective catalyst that allows cross‐linked ferrocenyl‐containing silicones (silicone rubbers) to be obtained with no visible mechanical defects (bubbles or cracks) compared with Karstedt's catalyst. The ferrocene content of the ferrocenyl‐containing silicone rubbers was found to be approximately 50 wt.% by energy‐dispersive X‐ray analysis. Compared with cross‐linked non‐modified polymethylhydrosiloxanes, the ferrocenyl‐containing silicone rubbers exhibited improved tensile properties (the tensile strength increased from 0.47 to 0.75 MPa) and a 1.5–2.5 times lower cross‐linking degree. The surface resistivity of the ferrocenyl‐containing silicone rubbers (50 wt.% ferrocenyl units) was approximately 7 × 109 Ω/□, which was 10,000 times lower than that of pure polymethylhydrosiloxane. The obtained flexible electroactive ferrocenyl‐containing silicone rubbers can potentially be applied as coatings for electronic and electrostatic‐sensitive devices, interfaces, and sensors.
This review is dedicated to versatile silicone rubber composites based on carbon nanotube/graphene (CNT/G) hybrid fillers. Due to their unique mechanical, electrical, thermal, and biological properties, such composites have enormous potential for medical, environmental, and electronics applications. In the scope of this paper, we have explored CNT/graphene/silicone composites with a different morphology, analyzed the synergistic effect of hybrid fillers on various properties of silicone composites, and observed the existing approaches for the fabrication of hybrid composites with a seamless, assembled, and/or foamed structure. In conclusion, current challenges and future prospects for silicone composites based on CNTs and graphene have been thoroughly discussed.
In this paper, we report a cost-effective and scalable approach to produce highly homogeneous graphene and CNT-based silicone composites with potential applications in diverse fields of research, including biosensors and wearable electronics. This approach includes the fabrication of hybrid fillers based on few-layer graphene and CNTs by water solution blending and manufacturing of graphene/CNT/PDMS composites through calendering in a three-roll mill. The influence of processing parameters, the graphene/CNT ratio, and hybrid filler loading was thoroughly investigated, and the optimal parameters for producing hybrid composites with superior electrical and mechanical properties were found. It was also confirmed that the graphene/CNT hybrid system exhibits a synergistic effect of non-covalent interactions between graphene sheets and CNT sidewalls. This synergistic effect prevents the aggregation of graphene sheets, facilitates the dispersion of graphene and CNTs in the silicone matrix, and contributes to the superior properties of hybrid composites compared to composites with either of these fillers alone.
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