In the present review, we focused on the fundamental concepts of hydrogels—classification, the polymers involved, synthesis methods, types of hydrogels, properties, and applications of the hydrogel. Hydrogels can be synthesized from natural polymers, synthetic polymers, polymerizable synthetic monomers, and a combination of natural and synthetic polymers. Synthesis of hydrogels involves physical, chemical, and hybrid bonding. The bonding is formed via different routes, such as solution casting, solution mixing, bulk polymerization, free radical mechanism, radiation method, and interpenetrating network formation. The synthesized hydrogels have significant properties, such as mechanical strength, biocompatibility, biodegradability, swellability, and stimuli sensitivity. These properties are substantial for electrochemical and biomedical applications. Furthermore, this review emphasizes flexible and self-healable hydrogels as electrolytes for energy storage and energy conversion applications. Insufficient adhesiveness (less interfacial interaction) between electrodes and electrolytes and mechanical strength pose serious challenges, such as delamination of the supercapacitors, batteries, and solar cells. Owing to smart and aqueous hydrogels, robust mechanical strength, adhesiveness, stretchability, strain sensitivity, and self-healability are the critical factors that can identify the reliability and robustness of the energy storage and conversion devices. These devices are highly efficient and convenient for smart, light-weight, foldable electronics and modern pollution-free transportation in the current decade.

This study considered the impacts of diesel–soybean biodiesel blends mixed with 3% cerium coated zinc oxide (Ce-ZnO) nanoparticles on the performance, emission, and combustion characteristics of a single cylinder diesel engine. The fuel blends were prepared using 25% soybean biodiesel in diesel (SBME25). Ce-ZnO nanoparticle additives were blended with SBME25 at 25, 50, and 75 ppm using the ultrasonication process with a surfactant (Span 80) at 2 vol.% to enhance the stability of the blend. A variable compression ratio engine operated at a 19.5:1 compression ratio (CR) using these blends resulted in an improvement in overall engine characteristics. With 50 ppm Ce-ZnO nanoparticle additive in SBME25 (SBME25Ce-ZnO50), the brake thermal efficiency (BTE) and heat release rate (HRR) increased by 20.66% and 18.1%, respectively; brake specific fuel consumption (BSFC) by 21.81%; and the CO, smoke, and hydrocarbon (HC) decreased by 30%, 18.7%, and 21.5%, respectively, compared to SBME25 fuel operation. However, the oxides of nitrogen slightly rose for all the nanoparticle added blends. As such, 50 ppm of Ce-ZnO nanoparticle in the blend is a potent choice for the enhancement of engine performance, combustion, and emission characteristics.

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The present investigation is directed towards synthesis of zinc oxide (ZnO) nanoparticles and steady blending with soybean biodiesel (SBME25) to improve the fuel properties of SBME25 and enhance the overall characteristics of a variable compression ratio diesel engine. The soybean biodiesel (SBME) was prepared using the transesterification reaction. Numerous characterization tests were carried out to ascertain the shape and size of zinc oxide nanoparticles. The synthesized asymmetric ZnO nanoparticles were dispersed in SBME25 at three dosage levels (25, 50, and 75 ppm) with sodium dodecyl benzene sulphonate (SDBS) surfactant using the ultrasonication process. The quantified physicochemical properties of all the fuels blends were in symmetry with the American society for testing and materials (ASTM) standards. Nanofuel blends demonstrated enhanced fuel properties compared with SBME25. The engine was operated at two different compression ratios (18.5 and 21.5) and a comparison was made, and best fuel blend and compression ratio (CR) were selected. Fuel blend SBME25ZnO50 and compression ratio (CR) of 21.5 illustrated an overall enhancement in engine characteristics. For SBME25ZnO50 and CR 21.5 fuel blend, brake thermal efficiency (BTE) increased by 23.2%, brake specific fuel consumption (BSFC) were reduced by 26.66%, and hydrocarbon (HC), CO, smoke, and CO2 emissions were reduced by 32.234%, 28.21% 22.55% and 21.66%, respectively; in addition, the heat release rate (HRR) and mean gas temperature (MGT) improved, and ignition delay (ID) was reduced. In contrast, the NOx emissions increased for all the nanofuel blends due to greater supply of oxygen and increase in the temperature of the combustion chamber. At a CR of 18.5, a similar trend was observed, while the values of engine characteristics were lower compared with CR of 21.5. The properties of nanofuel blend SBME25ZnO50 were in symmetry and comparable to the diesel fuel.

This study aims to investigate a CI diesel engine characteristic of diesel-biodiesel blend with oxygenated alcohols and nanoparticle fuel additives. Biodiesel was synthesized from a complementary palm-sesame oil blend using an ultrasound-assisted transesterification process. B30 was mixed with fuel additives as the base fuel to form ternary blends in different proportions before engine testing. The oxygenated alcohols (DMC and DEE) and nanoparticles

The present investigation uses a blend of Nigella sativa biodiesel, diesel, n-butanol, and graphene oxide nanoparticles to enhance the performance, combustion and symmetric characteristics and to reduce the emissions from the diesel engine of a modified common rail direct injection (CRDI). A symmetric toroidal-type combustion chamber and a six-hole solenoid fuel injector were used in the current investigation. The research aimed to study the effect of two fuel additives, n-butanol and synthesized asymmetric graphene oxide nanoparticles, in improving the fuel properties of Nigella sativa biodiesel (NSME25). The concentration of n-butanol (10%) was kept constant, and asymmetric graphene oxide nano-additive and sodium dodecyl benzene sulphonate (SDBS) surfactant were added to n-butanol and NSME25 in the form of nanofluid in varying proportions. The nanofluids were prepared using a probe sonication process to prevent nanoparticles from agglomerating in the base fluid. The process was repeated for biodiesel, n-butanol and nanofluid, and four different stable and symmetric nanofuel mixtures were prepared by varying the graphene oxide (30, 60, 90 and 120 ppm). The nanofuel blend NSME25B10GO90 displayed an enhancement in the brake thermal efficiency (BTE) and a reduction in brake-specific fuel consumption (BSFC) at maximum load due to high catalytic activity and the enhanced microexplosion phenomenon developed by graphene oxide nanoparticles. The heat release rate (HRR), in-cylinder temperature increased, while exhaust gas temperature (EGT) decreased. Smoke, hydrocarbon (HC), carbon monoxide (CO2) and carbon monoxide (CO) emissions also fell, in a trade-off with marginally increased NOx, for all nanofuel blends, compared with Nigella sativa biodiesel. The results obtained indicates that 90 ppm of graphene oxide nanoparticles and 10% n-butanol in Nigella sativa biodiesel are comparable with diesel fuel.

Rapid depletion in fossil fuels, inflation in petroleum prices, and rising energy demand have forced towards alternative transport fuels. Among these alternative fuels, diesel-ethanol and diesel-biodiesel blends gain the most attention due to their quality characteristics and environmentally friendly nature. The viscosity and density of these biodiesel blends are slightly higher than diesel, which is a significant barrier to the commercialization of biodiesel. In this study, the density and viscosity of 30 different ternary biodiesel blends was investigated at 15 °С and 40 °С, respectively. Different density and viscosity models were developed and tested on biodiesel blends soured from different feedstock’s including palm, coconut, soybean, mustard, and calophyllum oils. The prognostic ability and precisions of these developed models was assessed statistically using Absolute Percentage Error (APE) and Mean Absolute Percentage Error (MAPE). The MAPE of 0.045% and 0.085% for density model and 1.85%, 1.41%, 3.48% and 2.27%, 1.85%, 3.50% for viscosity models were obtained on % volume and % mass basis. These developed correlations are useful for ternary biodiesel blends where alcohols are the part of biodiesel blends. The modeled values of densities and viscosities of ternary blends were significantly comparable with the measured densities and viscosities, which are feasible to avoid the harm of vehicles’ operability.

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