Stabilizing the polysulfide shuttle while ensuring high sulfur loading holds the key to realizing high theoretical energy of lithium-sulfur (Li-S) batteries. Herein, we present an electrocatalysis approach to demonstrate preferential adsorption of a soluble polysulfide species, formed during discharge process, toward the catalyst anchored sites of graphene and their efficient transformation to long-chain polysulfides in the subsequent redox process. Uniform dispersion of catalyst nanoparticles on graphene layers has shown a 40% enhancement in the specific capacity over pristine graphene and stability over 100 cycles with a Coulombic efficiency of 99.3% at a current rate of 0.2 C. Interaction between electrocatalyst and polysulfides has been evaluated by conducting X-ray photoelectron spectroscopy and electron microscopy studies at various electrochemical conditions.
Lithium-sulfur (Li-S) chemistry is projected to be one of the most promising for next-generation battery technology, and controlling the inherent "polysulfide shuttle" process has become a key research topic in the field. Regulating intermediary polysulfide dissolution by understanding the metamorphosis is essential for realizing stable and high-energy-density Li-S batteries. As of yet, a clear consensus on the basic surface/interfacial properties of the sulfur electrode has not been achieved, although the catalytic phenomenon has been shown to result in enhanced cell stability. Herein, we present evidence that the polysulfide shuttle in a Li-S battery can be stabilized by using electrocatalytic transition metal dichalcogenides (TMDs). Physicochemical transformations at the electrode/electrolyte interface of atomically thin monolayer/few-layer TMDs were elucidated using a combination of spectroscopic and microscopic analysis techniques. Preferential adsorption of higher order liquid polysulfides and subsequent conversion to lower order solid species in the form of dendrite-like structures on the edge sites of TMDs have been demonstrated. Further, detailed electrochemical properties such as activation energy, exchange current density, rate capabilities, cycle life, etc. have been investigated by synthesizing catalytically active nanostructured TMDs in bulk quantity using a liquid-based shear-exfoliation method. Unveiling a specific capacity of 590 mAh g at 0.5 C rate and stability over 350 cycles clearly indicates yet another promising application of two-dimensional TMDs.
With the ongoing global effort to reduce greenhouse gas emission and dependence on oil, electrical energy storage (EES) devices such as Li-ion batteries and supercapacitors have become ubiquitous. Today, EES devices are entering the broader energy use arena and playing key roles in energy storage, transfer, and delivery within, for example, electric vehicles, large-scale grid storage, and sensors located in harsh environmental conditions, where performance at temperatures greater than 25 °C are required. The safety and high temperature durability are as critical or more so than other essential characteristics (e.g., capacity, energy and power density) for safe power output and long lifespan. Consequently, significant efforts are underway to design, fabricate, and evaluate EES devices along with characterization of device performance limitations such as thermal runaway and aging. Energy storage under extreme conditions is limited by the material properties of electrolytes, electrodes, and their synergetic interactions, and thus significant opportunities exist for chemical advancements and technological improvements. In this review, we present a comprehensive analysis of different applications associated with high temperature use (40-200 °C), recent advances in the development of reformulated or novel materials (including ionic liquids, solid polymer electrolytes, ceramics, and Si, LiFePO, and LiMnO electrodes) with high thermal stability, and their demonstrative use in EES devices. Finally, we present a critical overview of the limitations of current high temperature systems and evaluate the future outlook of high temperature batteries with well-controlled safety, high energy/power density, and operation over a wide temperature range.
Lithium Sulfur (Li/S) chemistries are amongst the most promising next-generation battery technologies due to their high theoretical energy density. However, the detrimental effects of their intermediate byproducts, polysulfides (PS), have to be resolved to realize these theoretical performance limits. Confined approaches on using porous carbons to entrap PS have yielded limited success. In this study, we deviate from the prevalent approach by introducing catalysis concept in Li/S battery configuration. Engineered current collectors were found to be catalytically active towards PS, thereby eliminating the need for carbon matrix and their processing obligatory binders, additives and solvents. We reveal substantial enhancement in electrochemical performance and corroborate our findings using a detailed experimental parametric study involving variation of several kinetic parameters such as surface area, temperature, current rate and concentration of PS. The resultant novel battery configuration delivered a discharge capacity of 700 mAh g−1 with the two dimensional (2D) planar Ni current collectors and an enhancement in the capacity up to 900 mAh g−1 has been realized using the engineered three dimensional (3D) current collectors. The battery capacity has been tested for stability over 100 cycles of charge-discharge.
A review highlighting the unique chemistry of quinones and associated polymers as nature-derived electrode materials for green battery applications.
Monolayer transition metal dichalcogenides (TMD) have numerous potential applications in ultrathin electronics and photonics. The exposure of TMD-based devices to light generates photo-carriers resulting in an enhanced conductivity, which can be effectively used, e.g., in photodetectors. If the photo-enhanced conductivity persists after removal of the irradiation, the effect is known as persistent photoconductivity (PPC). Here we show that ultraviolet light (λ = 365 nm) exposure induces an extremely long-living giant PPC (GPPC) in monolayer MoS2 (ML-MoS2) field-effect transistors (FET) with a time constant of ~30 days. Furthermore, this effect leads to a large enhancement of the conductivity up to a factor of 107. In contrast to previous studies in which the origin of the PPC was attributed to extrinsic reasons such as trapped charges in the substrate or adsorbates, we show that the GPPC arises mainly from the intrinsic properties of ML-MoS2 such as lattice defects that induce a large number of localized states in the forbidden gap. This finding is supported by a detailed experimental and theoretical study of the electric transport in TMD based FETs as well as by characterization of ML-MoS2 with scanning tunneling spectroscopy, high-resolution transmission electron microscopy, and photoluminescence measurements. The obtained results provide a basis for the defect-based engineering of the electronic and optical properties of TMDs for device applications.
Lithium batteries that could be charged on exposure to sunlight will bring exciting new energy storage technologies. Here, we report a photorechargeable lithium battery employing nature-derived organic molecules as a photoactive and lithium storage electrode material. By absorbing sunlight of a desired frequency, lithiated tetrakislawsone electrodes generate electron–hole pairs. The holes oxidize the lithiated tetrakislawsone to tetrakislawsone while the generated electrons flow from the tetrakislawsone cathode to the Li metal anode. During electrochemical operation, the observed rise in charging current, specific capacity, and Coulombic efficiency under light irradiation in contrast to the absence of light indicates that the quinone-based organic electrode is acting as both photoactive and lithium storage material. Careful selection of electrode materials with optimal bandgap to absorb the intended frequency of sunlight and functional groups to accept Li-ions reversibly is a key to the progress of solar rechargeable batteries.
Growth of vertically aligned carbon nanotube (CNT) forests is highly sensitive to the nature of the substrate. This constraint narrows the range of available materials to just a few oxide-based dielectrics and presents a major obstacle for applications. Using a suspended monolayer, we show here that graphene is an excellent conductive substrate for CNT forest growth. Furthermore, graphene is shown to intermediate growth on key substrates, such as Cu, Pt, and diamond, which had not previously been compatible with nanotube forest growth. We find that growth depends on the degree of crystallinity of graphene and is best on mono- or few-layer graphene. The synergistic effects of graphene are revealed by its endurance after CNT growth and low contact resistances between the nanotubes and Cu. Our results establish graphene as a unique interface that extends the class of substrate materials for CNT growth and opens up important new prospects for applications.
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