Material composition engineering and device fabrication of perovskite nanocrystals (PNCs) in solution can introduce organic contamination and entail several synthetic, processing, and stabilization steps. We report three-dimensional (3D) direct lithography of PNCs with tunable composition and bandgap in glass. The halide ion distribution was controlled at the nanoscale with ultrafast laser–induced liquid nanophase separation. The PNCs exhibit notable stability against ultraviolet irradiation, organic solution, and high temperatures (up to 250°C). Printed 3D structures in glass were used for optical storage, micro–light emitting diodes, and holographic displays. The proposed mechanisms of both PNC formation and composition tunability were verified.

Enhancement of light extraction from an integrated ZnO nanotips/GaN light emitting diode (LED) is demonstrated. The device is composed of a GaN LED with a Ga-doped ZnO (GZO) transparent conductive layer and ZnO nanotips grown on GZO for light extraction. The light output power of a ZnO nanotips/GZO/GaN LED exhibits 1.7 times enhancement, in comparison with a conventional Ni∕Au p-metal LED. The higher emission efficiency is attributed to the enhanced light transmission and scattering in the ZnO∕GaN multilayer.

We describe the fabrication of a Mach-Zehnder optical modulator in LiNbO 3 by femtosecond laser micromachining, which is composed of optical waveguides inscripted by a femtosecond laser and embedded microelectrodes subsequently fabricated using femtosecond laser ablation and selective electroless plating. A half-wave voltage close to 19 V is achieved at a wavelength of 632.8 nm with an interaction length of 2.6 mm. This simple and cost-effective technique opens up new opportunities for fabricating integrated electro-optic devices. © 2008 Optical Society of America OCIS codes: 130.0250, 140.3390, 230.2090 Lithium niobate ͑LiNbO 3 ͒ is one of the most widely used nonlinear optic materials in integrated optics owing to its excellent nonlinear optical and electrooptic (EO) properties. Integrated EO devices based on waveguiding structures such as optical switches [1] and modulators [2,3] have gained significant attention. Conventionally, the waveguide fabrication is based on titanium diffusion or proton exchange, which permits fabrication of channel waveguides only close to the surface [4]. Recently, it has been demonstrated that buried optical waveguides in LiNbO 3 can be fabricated by femtosecond laser inscription [5], which opens the possibility to write 3D optical circuits in the crystal. Various fabrication parameters have been optimized by several groups [6][7][8], such as wavelength, repetition rate, polarization, pulse width, pulse energy, focusing geometry, and scanning speed. To realize integrated EO devices, it is further crucial to design and fabricate microelectrodes, which are usually obtained by use of lithographic methods. However, owing to the inherently planar nature of the lithographic process, this technique is limited in its capability to produce 3D structures. Furthermore, because the optical waveguides fabricated by femtosecond laser inscription usually are deeply buried in the crystal, the conventional surface electrodes give rise to weak EO interaction. As a simple and costeffective technique, laser-induced selective electroless deposition has been widely investigated, because it does not require fabrication steps involved in the traditional lithographic technique, such as deposition of thin layers of metals, pattern etching, and so on [9,10]. Recently, we developed a technique for selective metallization in LiNbO 3 using femtosecond-laser ablation and femtosecond-laser-assisted selective electroless plating, which allows for fabricating microelectrodes deeply embedded in LiNbO 3 [11]. In this Letter, we report the integration of embedded microelectrodes and optical waveguides in LiNbO 3 using a femtosecond laser. Based on this technique, a Mach-Zehnder interferometer (MZI) EO modulator in an x-cut LiNbO 3 crystal is demonstrated.For the fabrication of waveguides and electrodes, a Ti:sapphire laser system (Legend USP, Coherent Inc.) with an operation wavelength of 800 nm, a pulse width of ϳ40 fs, and a repetition rate of 1 KHz was used. Commercially available MgO-doped x-cut LiNbO 3 crystals...

Void evolution in silicon under inert and dry oxidizing ambient annealing and the role of a Si1−xGex epilayer cap J. Appl. Phys. 112, 054909 (2012) Predicting effective permittivity of composites containing conductive inclusions at microwave frequencies AIP Advances 2, 032109 (2012) Computational measurement of void percolation thresholds of oblate particles and thin plate composites J. Appl. Phys. 111, 124903 (2012) Vacancy clustering and its dissociation process in electroless deposited copper films studied by monoenergetic positron beams J. Appl. Phys. 111, 104506 (2012) A molecular "phase ordering" phase transition leading to a modulated aperiodic composite in n-heptane/urea

We report selective metallization on surfaces of insulators (glass slides and lithium niobate crystal) based on femtosecond laser modification combined with electroless plating. The process is mainly composed of four steps: (1) formation of silver nitrate thin films on the surfaces of glass or crystal substrates; (2) generation of silver particles in the irradiated area by femtosecond laser direct writing; (3) removal of unirradiated silver nitrate films; and (4) selective electroless plating in the modified area. We discuss the mechanism of selective metallization on the insulators. Moreover, we investigate the electrical and adhesive properties of the copper microstructures patterned on the insulator surfaces, showing great potential of integrating electrical functions into lab-on-a-chip devices.

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The structural evolution from void modification to self-assembled nanogratings in fused silica is observed for moderate (NA > 0.4) focusing conditions. Void formation, appears before the geometrical focus after the initial few pulses and after subsequent irradiation, nanogratings gradually occur at the top of the induced structures. Nonlinear Schrödinger equation based simulations are conducted to simulate the laser fluence, intensity and electron density in the regions of modification. Comparing the experiment with simulations, the voids form due to cavitation in the regions where electron density exceeds 10²⁰ cm^-3 but is below critical. In this scenario, the energy absorption is insufficient to reach the critical electron density that was once assumed to occur in the regime of void formation and nanogratings, shedding light on the potential formation mechanism of nanogratings.

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