Solution-processable inks based on lithium titanate with a conductive network architecture, toward high-rate lithium-ion batteries (LIBs) with a customized configuration are developed. The inks, with tunable viscosity, are compatible for on-demand coating techniques. The lithium titanate electrode derived from these inks exhibits excellent high-rate capacity (≈124 mA h g(-1) at 90 C, 15.7 A g(-1) ) after 1000 cycles.
Lithium-ion batteries (LIBs) are primary energy storage devices to power consumer electronics and electric vehicles, but their capacity is dramatically decreased at ultrahigh charging/discharging rates. This mainly originates from a high Li-ion/electron transport barrier within a traditional electrode, resulting in reaction polarization issues. To address this limitation, a functionally layer-graded electrode was designed and fabricated to decrease the charge carrier transport barrier within the electrode. As a proof-of-concept, functionally layer-graded electrodes composing of TiO (B) and reduced graphene oxide (RGO) exhibit a remarkable capacity of 128 mAh g at a high charging/discharging rate of 20 C (6.7 A g ), which is much higher than that of a traditionally homogeneous electrode (74 mAh g ) with the same composition. This is evidenced by the improvement of effective Li ion diffusivity as well as electronic conductivity in the functionally layer-graded electrodes.
Silver sulfadiazine (SSD) is a useful antimicrobial agent for wound treatment. However, recent findings indicate that conventional SSD cream has several drawbacks for use in treatments. Bacterial cellulose (BC) is a promising material for wound dressing due to its outstanding properties of holding water, strength and degradability. Unfortunately, BC itself exhibits no antimicrobial activity. A combination of SSD and BC is envisaged to form a new class of wound dressing with both antimicrobial activity and biocompatibility, which has not been reported to date. To achieve antimicrobial activity, SSD particles were impregnated into BC by immersing BC into SSD suspension after ultrasonication, namely SSD-BC. Parameters influencing SSD-BC impregnation were systematically studied. Optimized conditions of sonication time for no less than 90 min and the proper pH value between 6.6 and 9.0 were suggested. The absorption of SSD onto the BC nanofibrous network was revealed by XRD and SEM analyses. The SSD-BC membranes exhibited significant antimicrobial activities against Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus evaluated by the disc diffusion method. In addition, the favorable biocompatibility of SSD-BC was verified by MTT colorimetry, epidermal cell counting method and optical microscopy. The results demonstrate the potential of SSD-BC membranes as a new class of antimicrobial and biocompatible wound dressing.
Developing earth-abundant, highly active, and durable electrocatalysts for the oxygen evolution reaction (OER) is very important for many renewable energy conversion processes. Herein, we report a novel OER electrocatalyst of NiCo layered double hydroxide@NiCo-hydroxysulfide (NiCo-LDH@HOS) nanosheet arrays, which are prepared by a rapid room-temperature sulfurization of the surface of NiCo-LDH nanosheets grown on Ni foam. The surface sulfurization exerts important influences/changes on the structure, composition, surface properties and chemistry of NiCo-LDH. After surface sulfurization, the resulted NiCohydroxysulfide layer armor improved electrical conductivity and chemical resistance to alkaline electrolyte, delivers a stable current density of 10.0 mA cm −2 at a low overpotential of 293 mV in 0.1 M KOH solution, maintaining high stability during a 62 h test. The achieved enhanced oxygen evolution activity and improved durability are superior to those of NiCo-LDH nanosheets and benchmark commercial RuO 2 . This example of NiCo-LDH@HOS obtained via surface sulfurization with enhanced OER electrocatalysis performance, highlights an important strategy to fabricate high-performance metal hydroxide/hydroxysulfides heterostructured catalysts for OER and other electrochemical storage and conversion progress.
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