We investigated the effects of the in situ thermal cleaning treatment of a (0001) sapphire substrate surface in hydrogen ambient on the structural, optical, and electrical properties of epitaxial GaN films grown by metalorganic chemical vapor deposition (MOCVD). Hall effect, X-ray diffraction (XRD), and photoluminescence measurements of GaN films grown at 1040 • C clearly indicate that the film quality is strongly affected by the thermal cleaning treatment of the substrate surface. GaN films under the optimized thermal cleaning treatment at 1070 • C for 10 min showed minimum full-widths at half maximum (FWHMs) of 273 arcsec and 728 arcsec for (002) and (102) XRD peaks, respectively. In addition, the FWHM of the band-edge emission peak was as narrow as 28.3 meV, and the intensity ratio between the band edge emission and the yellow band emission was as high as 100 at room temperature. It was also found that the roughness of sapphire surface was reduced after the thermal treatment.
Si delta-doping in the GaN layer has been successfully demonstrated by metalorganic chemical vapor deposition. From the capacitance-voltage measurement, a sharp carrier concentration profile with a full width at half-maximum of 4.1 nm has been achieved with a peak concentration of 9.8×1018 cm-3. Si delta-doping concentration increases and then decreases with an increase in delta-doping time, and the use of a post-purge step in the ammonia ambient reduces Si delta-doping concentration. This indicates that delta-doping concentration is limited by the Si desorption process due to high growth temperatures.
Si delta-doping in the GaN layer has been successfully demonstrated by low-pressure metalorganic chemical vapor deposition at a growth temperature of 1040 TC. Si delta-doping concentration increases and then decreases with an increase in delta-doping time. This indicates that delta-doping concentration is limited by the desorption process owing to much higher thermal decomposition efficiency of silane at high growth temperatures of GaN. In addition, it was observed that the use of a post-purge step in the ammonia ambient reduces Si delta-doping concentration. From capacitance-voltage measurement, a sharp carrier concentration profile with a full-width at half maximum of 4.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.