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A family of uranium diphosphonates have been hydrothermally synthesized through the reaction of ethylenediphosphonic acid (EDP, H4L) and uranyl nitrate/zinc uranyl acetate in the presence of organic templates, such as tetraethyl ammonium (NEt4(+)), 4,4'-bipyridine (bipy), and 1,10-phenanthroline (phen). The UO2(2+) in UO2(H2O)(H2L)(EDP-U1) is equatorially five-coordinated by four phosphonate groups and one aqua ligand, forming a pentagonal bipyramid. Each EDP ligand is doubly protonated and chelates three UO2(2+), resulting in a layered structure. Compounds (NEt4)2(UO2)3(HL)2(H2L)·4H2O (EDP-U2) and (H2bipy)UO2L (EDP-U3) have the same layered structure in which NEt4(+) and protonated bipy fill in the uranyl-phosphonate interlayers, respectively, and play a role to balance the negative charges. Different from that in EDP-U1, the UO2(2+) exists in the form of a UO6 tetragonal bipyramid and is surrounded by four different EDP ligands in EDP-U2 and EDP-U3. (Hphen)2(UO2)2(H2L)3 (EDP-U4) features a three-dimensional framework structure with large elliptical channels along the c axis (1.3 × 1.1 nm(2)). Monoprotonated phen molecules fill in these channels and hold together through strong π···π interactions. All of the four compounds have been characterized by IR and photoluminescent spectroscopy. Their characteristic emissions have been attributed as transition properties of uranyl cations. The ion-exchange study indicates that [Co(en)3](3+) could partially replace the protonated phen molecules.

A novel switching scheme for low energy charge-redistribution digital-to-analog converter (DAC) to be used in successive approximation register (SAR) analogue to-digital converters (ADCs) is presented which requires only 2 references, V REF and ground. With the monotonic capacitor switching procedure and C-2C dummy capacitor, the proposed switching scheme achieves 90.61% less switching energy, 74.7% less area and 41.18% less number of switches compared to conventional architecture, which results in an energy-efficient and switch-fewest switching scheme. Behavioral simulation results prove the effectiveness of the proposed switching scheme.

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In this paper we demonstrate a novel, all-optical differential current protection scheme. By monitoring the optical power reflected from two matched hybrid fiber Bragg grating current sensors and using a simple optoelectronic threshold detector, an immediate response to an increase in differential current is achieved. A preliminary laboratory embodiment is constructed in order to characterize the performance of the scheme. The proposed technique does not require a complex sensor interrogation scheme, usually characterized by a limited sampling frequency, and thus will be capable of facilitating inexpensive and fast-acting differential protection over long distances

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