Acceptor alloys based on n-type small molecular and fullerene derivatives are used to fabricate the ternary solar cell. The highest performance of optimized ternary device is 10.4%, which is the highest efficiency for one donor/two acceptors-based ternary systems. Three important parameters, J , V , and FF, of the optimized ternary device are all higher than the binary reference devices.
High-voltage lithium-ion batteries (HVLIBs) are considered as promising devices of energy storage for electric vehicle, hybrid electric vehicle, and other high-power equipment. HVLIBs require their own platform voltages to be higher than 4.5 V on charge. Lithium nickel manganese spinel LiNi0.5Mn1.5O4 (LNMO) cathode is the most promising candidate among the 5 V cathode materials for HVLIBs due to its flat plateau at 4.7 V. However, the degradation of cyclic performance is very serious when LNMO cathode operates over 4.2 V. In this review, we summarize some methods for enhancing the cycling stability of LNMO cathodes in lithium-ion batteries, including doping, cathode surface coating, electrolyte modifying, and other methods. We also discuss the advantages and disadvantages of different methods.
We have demonstrated a miniature biofuel cell (BFC) with single-walled carbon nanohorn (SWNH)-modified carbon fiber microelectrodes (CFMEs) as the substrate for the first time. The bioanode was constructed by using glucose dehydrogenase (GDH) as the biocatalyst on SWNHmodified CFMEs, where a highly efficient and stably confined electrocatalyst for the oxidation of the NADH co-factor of GDH was beforehand immobilized. Similarly, an electrically contacted bilirubin oxidase (BOD)-SWNHs/CFME was prepared as the biocathode, which showed direct bioelectrocatalytic functions for the reduction of O 2 to H 2 O. The maximum power output of the cell was 140 mW cm À2 at 0.51 V. Most interestingly, the present glucose/air BFC can directly harvest energy from different kinds of soft drinks, which could promise potential applications of the BFC as portable power sources.
The requirement of energy-storage equipment needs to develop the lithium ion battery (LIB) with high electrochemical performance. The surface modification of commercial LiFePO4 (LFP) by utilizing zeolitic imidazolate frameworks-8 (ZIF-8) offers new possibilities for commercial LFP with high electrochemical performances. In this work, the carbonized ZIF-8 (CZIF-8) was coated on the surface of LFP particles by the in situ growth and carbonization of ZIF-8. Transmission electron microscopy indicates that there is an approximate 10 nm coating layer with metal zinc and graphite-like carbon on the surface of LFP/CZIF-8 sample. The N2 adsorption and desorption isotherm suggests that the coating layer has uniform and simple connecting mesopores. As cathode material, LFP/CZIF-8 cathode-active material delivers a discharge specific capacity of 159.3 mAh g−1 at 0.1C and a discharge specific energy of 141.7 mWh g−1 after 200 cycles at 5.0C (the retention rate is approximate 99%). These results are attributed to the synergy improvement of the conductivity, the lithium ion diffusion coefficient, and the degree of freedom for volume change of LFP/CZIF-8 cathode. This work will contribute to the improvement of the cathode materials of commercial LIB.
Electronic supplementary materialThe online version of this article (doi:10.1007/s40820-017-0154-4) contains supplementary material, which is available to authorized users.
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