The frequency dependence of capacitance-voltage (C-V) and conductance-voltage (G/ω-V) characteristics of the Au/polyvinyl alcohol (Ni, Zn-doped)/n-Si Schottky barrier diodes (SBDs) was investigated in the frequency range of 3 kHz-3 MHz at room temperature by considering series resistance (Rs) and interface states (Nss) effects. The C-V and G/ω-V characteristics confirm that the Rs and Nss are important parameters that strongly influence the electrical parameters of SBDs. The C-V plots show an intersection point (∼2.9 V) at low frequencies (f ≤ 30 kHz) and then take negative values, which is known as negative capacitance (NC) behavior. The negativity of the C increases with the decreasing frequency in the forward bias voltage region, and this decrement in the NC corresponds to the increment in the conductance. Also, the forward bias C-V plots show an anomalous peak in the voltage range of 1.55–1.9 V depending on the frequency such that the anomalous peaks shift toward positive voltage values with the increasing frequency. The effect of Rs on the C is found appreciable at high frequencies. In addition, the values of Nss and Rs are found to decrease with the increasing frequency.
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