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In a medium term scenario hybrid powertrain and Internal Combustion Engine (ICE) downsizing represent the actual trend in vehicle technology to reduce fuel consumption and CO2 emission. Concerning downsizing concept, to maintain a reasonable power level in small engines, the application of turbocharging is mandatory both for spark ignited (SI) and compression ignited (CI) engines. Following this aspect, the possibility to couple an electric drive to the turbocharger (electric turbo compound) to recover the residual energy of the exhaust gases is becoming more and more attractive, as demonstrated by several studies around the world and by the current application in the F1 Championship. The present paper shows the first numerical results of a research program in collaboration between the Universities of Pisa and Genoa. This first study is focused on the evaluation of the benefits resulting from the application of an ETC (Electric Turbo Compound) to a small twin-cylinder SI engine (900 cm3). Starting from the experimental maps of two turbines and one compressor, the complete model of a turbocharged engine was created using the AVL BOOST one-dimension code. The numerical activity then moves to the whole vehicle/powertrain modelling, considering three driving cycles and two different vehicle configurations, in order to verify the effectiveness of the proposed ETC solution. Results show that the adoption of ETC is not advantageous if used for a conventional turbocharger turbine, if the target is to optimize the overall efficiency in one specific operating point of the ICE, like in the case of range-extended electric vehicles. Besides, ETC can slightly improve the average overall efficiency when the ICE must provide variable power output, as in the case of conventional or hybrid vehicles. However, the major benefits coming from ETC are the boost range extension in the lowest engine rotational speed region and a possible reduction of turbo lag, which are key points in parallel-hybrid and especially in conventional vehicles. Concerning the whole vehicle/powertrain simulation, first results show that the ETC does not improve fuel economy of the smaller vehicle, especially when employed in urban cycles. The ETC is much more advantageous in the case of the larger vehicle, particularly when extra-urban roads or motorways are considered

The present investigation represents a concrete example of complete valorization of Eucalyptus nitens biomass, in the framework of the circular economy. Autohydrolyzed-delignified Eucalyptus nitens was employed as a cheap cellulose-rich feedstock in the direct alcoholysis to n-butyl levulinate, adopting n-butanol as green reagent/reaction medium, very dilute sulfuric acid as a homogeneous catalyst, and different heating systems. The effect of the main reaction parameters to give n-butyl levulinate was investigated to check the feasibility of this reaction and identify the coarse ranges of the main operating variables of greater relevance. High n-butyl levulinate molar yields (35–40 mol%) were achieved under microwave and traditional heating, even using a very high biomass loading (20 wt%), an eligible aspect from the perspective of the high gravity approach. The possibility of reprocessing the reaction mixture deriving from the optimized experiment by the addition of fresh biomass was evaluated, achieving the maximum n-butyl levulinate concentration of about 85 g/L after only one microwave reprocessing of the mother liquor, the highest value hitherto reported starting from real biomass. The alcoholysis reaction was further optimized by Response Surface Methodology, setting a Face-Centered Central Composite Design, which was experimentally validated at the optimal operating conditions for the n-butyl levulinate production. Finally, a preliminary study of diesel engine performances and emissions for a model mixture with analogous composition to that produced from the butanolysis reaction was performed, confirming its potential application as an additive for diesel fuel, without separation of each component.

The increasing penetration of renewable energy sources in the electricity generation scenario forces to face new challenges to achieve an effective management of the power system both in technical and economic terms. Traditional energy storage solutions, like electrochemical cells and pumped hydro energy storage appear critical in terms of economic sustainability and site-dependency. The use of compressed air as energy storage has been investigated since the 20th century, but, in its first configuration, it was affected by site constraints as pumped hydro plants do. Liquid air energy storage has the chance to overcome those limits, but the experimental studies have far reached low efficiency. However, by rising the highest cycle temperature with the addiction of fossil fuel energy, these results can be largely improved.The paper deals with the thermodynamic analysis of a hybrid system including energy storage and production based on a liquid air energy storage plant where only oxygen is liquefied, while liquefied natural gas is used as fuel. In the production phase, liquefied oxygen and natural gas react in an oxy-combustion chamber where a large amount of water is added to keep the temperature at an acceptable level by evaporation. The system does not require an external water supply since all the water needed is produced by the cycle itself, allowing the plant to be placed also in remote areas with poor water resources. At the beginning of the cycle, both the reagents are liquid at very low temperature (below -150°C) and they need heat to be gasified; a large amount of this heat can be recovered from the combustion products, which, being cooled at suitable pressure, release liquid carbon dioxide which can thus be easily separated. Optimized arrangements, compared to the performances of the best available hybrid peak plants, even with sufficiently conservative hypotheses, reach high equivalent round trip efficiencies, even higher than 90%.Hybrid systems for storage and generation of electricity help keeping the balance between power generation and demand in the electrical systems having a high share of production from variable and stochastic renewable sources (such as solar photovoltaics and wind), thus enabling the system to have a high energy and economic-financial effectiveness in providing the grid with regulation services [1], even in systems with load and generation uncertainty [2]. These systems, jointly managed with renewable generation, enable creating integrated systems able to follow a guaranteed production program and, therefore, to participate in the electricity market, overcoming the dispatching priority method used for subsidizing the generation from renewables. Key features of these integrated hybrid systems can be: have a long-term electricity storage able to compensate the production surplus for at least one day (e.g. for a photovoltaic production system) or one week (e.g. for a wind power system), i.e. from ten to hundreds of equivalent running hours at rated power;