ElsevierFernández Domene, RM.; Sánchez Tovar, R.; Lucas-Granados, B.; Roselló-Márquez, G.; Garcia-Anton, J. (2017). A simple method to fabricate high-performance nanostructured WO3 photocatalysts with adjusted morphology in the presence of complexing agents. (J. .The rich and complex chemistry of tungsten was employed to synthesize innovative WO3 nanoplatelets/nanosheets by simple anodization in acidic electrolytes containing different concentrations of complexing agents or ligands, namely Fand H2O2. The morphological and photoelectrochemical properties of these nanostructures were characterized. The best of these nanostructures generated stable photocurrent densities of ca. 1.8 mA cm -2 at relatively low bias potentials (for WO3) of 0.7 VAg/AgCl under simulated solar irradiation, which can be attributed to a very high active surface area.This work demonstrates that the morphology and dimensions of these nanostructures, as well as their photoelectrochemical behavior, can be controlled by adjusting the ligand concentration in the electrolytes, hence providing an easy and non-expensive route to fabricate and customize high-performance nanostructured photocatalysts for clean energy production and environmental applications.
A visible-light driven photoelectrochemical degradation process has been applied to a solution polluted with the organophosphate insecticide chlorfenvinphos. Different WO3 nanosheets/nanorods have been used as photoanodes. These nanostructured electrodes have been fabricated by anodization of tungsten and, subsequently, they have been subjected to a thermal treatment (annealing). The combined influence of annealing temperature (400º C and 600º C) and operation pH (1 and 3) on the photoelectrocatalytic behavior of these nanorods has been examined through a statistical analysis. Morphological, structural and photoelectrochemical characterizations have also been carried out. The chlorfenvinphos degradation efficiency depended both on annealing temperature and, specially, operation pH. At pH 1 and using an annealing temperature of 600º C, chlorfenvinphos has been effectively degraded following pseudo-first order kinetics with a coefficient of 7.8×10 -3 min -1 , and notably mineralized (more than 65% of Total Organic Carbon decrease).
A photoelectrocatalyst consisting of WO3 nanosheets or nanorods has been synthesized by electrochemical anodization under hydrodynamic conditions, and has been used for the degradation of two toxic pesticides: chlorfenvinphos and bromacil. Nanostructures have been characterized by FESEM and Raman spectroscopy. Photoelectrochemical degradation tests have been carried out both for individual pesticide solutions and for a mixture solution, and the concentration evolution with time has been followed by UV-Vis spectrophotometry. For individual pesticides, pseudo-first order kinetic coefficients of 0.402 h -1 and 0.324 h -1 have been obtained for chlorfenvinphos and bromacil, respectively, while for the mixture solution, these kinetic coefficients have been 0.162 h -1 and 0.408 h -1 . The change in behavior towards pesticide degradation depending on whether individual or mixture solutions were used might be indicative of a competitive process between the two pesticide molecules when interacting with the WO3 nanostructures surface or when approaching the semiconductor/electrolyte interface.
In this study, WO3 nanostructures were synthesized by the electrochemical anodization technique to use them on the degradation of persistent organic compounds such as the pesticide fenamiphos. The acids electrolyte used during the anodization were two different: 1.5 M H2SO4 -0.05 M H2O2 and 1.5 M CH4O3S -0.05 M H2O2. Once the samples have been manufactured, they have been subjected to different tests to analyze the properties of the nanostructures. With Field Emission Scanning Electron Microscopy (FE-SEM) the samples have been examined morphologically, their composition and crystallinity has been studied through Raman Spectroscopy and their photoelectrochemical behaviour by Photoelectrochemical Impedance Spectroscopy (PEIS). Finally, degradation tests have been carried out using the technique known as photoelectrocatalysis (PEC). The conditions that were applied in this technique were a potential of 1 VAg/AgCl and simulated solar illumination. The degradation process was monitored by UV-Visible and High-Performance liquid Chromatography (HPLC) to control the course of the experiment. The nanostructures obtained with 1.5 M CH4O3S -0.05 M H2O2 electrolyte showed a better photoelectrochemical behaviour than nanostructures synthesized with 1.5 M H2SO4 -0.05 M H2O2. The fenamiphos degradation was achieved at 2 hours of experiment and the intermediate formation was noticed at 1 hour of PEC experiment.
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