Tin halide perovskites attract incremental attention to deliver lead‐free perovskite solar cells. Nevertheless, disordered crystal growth and low defect formation energy, related to Sn(II) oxidation to Sn(IV), limit the efficiency and stability of solar cells. Engineering the processing from perovskite precursor solution preparation to film crystallization is crucial to tackle these issues and enable the full photovoltaic potential of tin halide perovskites. Herein, the ionic liquid n‐butylammonium acetate (BAAc) is used to tune the tin coordination with specific O…Sn chelating bonds and NH…X hydrogen bonds. The coordination between BAAc and tin enables modulation of the crystallization of the perovskite in a thin film. The resulting BAAc‐containing perovskite films are more compact and have a preferential crystal orientation. Moreover, a lower amount of Sn(IV) and related chemical defects are found for the BAAc‐containing perovskites. Tin halide perovskite solar cells processed with BAAc show a power conversion efficiency of over 10%. This value is retained after storing the devices for over 1000 h in nitrogen. This work paves the way toward a more controlled tin‐based perovskite crystallization for stable and efficient lead‐free perovskite photovoltaics.

Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilized the perovskite black phase and improved solar cell performance using the ordered dipolar structure of β-poly(1,1-difluoroethylene) to control perovskite film crystallization and energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimeters and 23.1% over 1 square centimeter, which retained 96 and 88% of the efficiency after 1000 hours of 1-sun maximum power point tracking at 25° and 75°C, respectively. Devices under rapid thermal cycling between −60° and +80°C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.

The CAPRI and CASP prediction experiments have demonstrated the power of community wide tests of methodology in assessing the current state of the art and spurring progress in the very challenging areas of protein docking and structure prediction. We sought to bring the power of community wide experiments to bear on a very challenging protein design problem that provides a complementary but equally fundamental test of current understanding of protein-binding thermodynamics. We have generated a number of designed protein-protein interfaces with very favorable computed binding energies but which do not appear to be formed in experiments, suggesting there may be important physical chemistry missing in the energy calculations. 28 research groups took up the challenge of determining what is missing: we provided structures of 87 designed complexes and 120 naturally occurring complexes and asked participants to identify energetic contributions and/or structural features that distinguish between the two sets. The community found that electrostatics and solvation terms partially distinguish the designs from the natural complexes, largely due to the non-polar character of the designed interactions. Beyond this polarity difference, the community found that the designed binding surfaces were on average structurally less embedded in the designed monomers, suggesting that backbone conformational rigidity at the designed surface is important for realization of the designed function. These results can be used to improve computational design strategies, but there is still much to be learned; for example, one designed complex, which does form in experiments, was classified by all metrics as a non-binder.

The high‐voltage and low‐current output characteristics of a triboelectric nanogenerator (TENG) make itself difficult for directly powering small electronic devices. A power management circuit (PMC) is indispensable to address the impedance mismatch issue. In this paper, a TENG with a unidirectional switch (TENG‐UDS) is developed, which can provide the maximized output energy regardless of the load resistance. A passive PMC with a simple structure and high energy storage efficiency is designed based on this TENG‐UDS, which is made up of all passive electronic components, including an inductor, a diode, and a capacitor. Theoretical calculations show that the theoretical energy storage efficiency of the passive PMC can reach 75.8%. In the actual experiment of charging a capacitor, the measured energy storage efficiency can reach 48.0%. It is demonstrated that the electronic watch and high‐brightness quantum dot light‐emitting diode can be driven by using the TENG‐UDS with the passive PMC, which cannot be achieved without the PMC. The passive PMC for TENG‐UDS has the advantages of simple structure, low energy consumption, and high energy storage efficiency, which provides a promising method for the power management and practical application of TENG.

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The hyper-singular boundary integral equation method of crack analysis in three-dimensional transversely isotropic magnetoelectroelastic media is proposed. Based on the fundamental solutions or Green's functions of three-dimensional transversely isotropic magnetoelectroelastic media and the corresponding Somigliana identity, the boundary integral equations for a planar crack of arbitrary shape in the plane of isotropy are obtained in terms of the extended displacement discontinuities across crack faces. The extended displacement discontinuities include the displacement discontinuities, the electric potential discontinuity and the magnetic potential discontinuity, and correspondingly the extended tractions on crack face represent the conventional tractions, the electric displacement and the magnetic induction boundary values. The near crack tip fields and the intensity factors in terms of the extended displacement discontinuities are derived by boundary integral equation approach. A solution method is proposed by use of the analogy between the boundary integral equations of the magnetoelectroelastic media and the purely elastic materials. The influence of different electric and magnetic boundary conditions, i.e., electrically and magnetically impermeable and permeable conditions, electrically impermeable and magnetically permeable condition, and electrically permeable and magnetically impermeable condition, on the solutions is studied. The crack opening model is proposed to consider the real crack opening and the electric and magnetic fields in the crack cavity under combined mechanical-electric-magnetic loadings. An iteration approach is presented for the solution of the non-linear model. The exact solution is obtained for the case of uniformly applied loadings on the crack faces. Numerical results for a square crack under different electric and magnetic boundary conditions are displayed to demonstrate the proposed method.

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