Tin and its compounds hold promise for the development of high-capacity anode materials that could replace graphitic carbon used in current lithium-ion batteries. However, the introduced porosity in current electrode designs to buffer the volume changes of active materials during cycling does not afford high volumetric performance. Here, we show a strategy leveraging a sulfur sacrificial agent for controlled utility of void space in a tin oxide/graphene composite anode. In a typical synthesis using the capillary drying of graphene hydrogels, sulfur is employed with hard tin oxide nanoparticles inside the contraction hydrogels. The resultant graphene-caged tin oxide delivers an ultrahigh volumetric capacity of 2123 mAh cm–3 together with good cycling stability. Our results suggest not only a conversion-type composite anode that allows for good electrochemical characteristics, but also a general synthetic means to engineering the packing density of graphene nanosheets for high energy storage capabilities in small volumes.
Wear mechanisms including fracture and plastic deformation at the nanoscale are central to understand sliding contacts. Recently, the combination of tip-induced material erosion with the sensing capability of secondary imaging modes of AFM, has enabled a slice-and-view tomographic technique named AFM tomography or Scalpel SPM. However, the elusive laws governing nanoscale wear and the large quantity of atoms involved in the tip-sample contact, require a dedicated mesoscale description to understand and model the tip-induced material removal. Here, we study nanosized sliding contacts made of diamond in the regime whereby thousands of nm3 are removed. We explore the fundamentals of high-pressure tip-induced material removal for various materials. Changes in the load force are systematically combined with AFM and SEM to increase the understanding and the process controllability. The nonlinear variation of the removal rate with the load force is interpreted as a combination of two contact regimes each dominating in a particular force range. By using the gradual transition between the two regimes, (1) the experimental rate of material eroded on each tip passage is modeled, (2) a controllable removal rate below 5 nm/scan for all the materials is demonstrated, thus opening to future development of 3D tomographic AFM.
Straining to make a transistor
The use of carbon nanotubes (CNTs) as short-channel-length transistors will require control of their chirality, which determines whether they are semiconducting or metallic and if they form strong, low-resistance contacts. Tang
et al
. fabricated CNT intramolecular transistors by progressive heating and straining of individual CNTs within a transmission electron microscope. Changes to chirality along sections of the nanotube created metallic-to-semiconducting transitions. A semiconducting nanotube channel was covalently bonded to the metallic nanotube source and drain regions. The resulting CNT intramolecular transistors had channel lengths as short as 2.8 nanometers. —PDS
When two macroscopic objects touch, the real contact
typically
consists of multiple surface asperities that are deformed under the
pressure that holds the objects together. Application of a shear force
makes the objects slide along each other, breaking the initial contacts.
To investigate how the microscopic shear force at the asperity level
evolves during the transition from static to dynamic friction, we
apply a fluorogenic mechanophore to visualize and quantify the local
interfacial shear force. When a contact is broken, the shear force
is released and the molecules return to their dark state, allowing
us to dynamically observe the evolution of the shear force at the
sliding contacts. We find that the macroscopic coefficient of friction
describes the microscopic friction well, and that slip propagates
from the edge toward the center of the macroscopic contact area before
sliding occurs. This allows for a local understanding of how surfaces
start to slide.
Mechanical resonators have wide applications in sensing bio-chemical substances, and provide an accurate method to measure the intrinsic elastic properties of oscillating materials. A high resonance order with high response frequency and a small resonator mass are critical for enhancing the sensitivity and precision. Here, we report on the realization and direct observation of high-order and high-frequency silicon nanowire (Si NW) resonators. By using an oscillating electric-field for inducing a mechanical resonance of singlecrystalline Si NWs inside a transmission electron microscope (TEM), we observed resonance up to the 5 th order, for both normal and parametric modes at $100 MHz frequencies. The precision of the resonant frequency was enhanced, as the deviation reduced from 3.14% at the 1 st order to 0.25% at the 5 th order, correlating with the increase of energy dissipation. The elastic modulus of Si NWs was measured to be $169 GPa in the [110] direction, and size scaling effects were found to be absent down to the $20 nm level.
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