In this paper, different types of polyurethane foams (PUR) having various chemical compositions have been produced with a specific density to monitor the microstructure as much as possible. The foam may have a preferential orientation in the cell structure. The cellular polyurethane tends to have stubborn, typical cellular systems with strong overlap reversibility. Free expansion under atmospheric pressure enables formulas to grow until they are refined. Moreover, the physicochemical characterization of the developed foams was carried out. They later are described by apparent density, Shore hardness, Raman spectroscopy analysis, X-Ray diffraction analysis, FTIR, TGA, DSC, and compression tests. The detailed structural characterization was used by scanning electron microscope (SEM) and an optical microscope (MO) to visualize the alveolar polymer’s semi-opened cells, highlighting the opened-cell morphology and chemical irregularities. Polyurethane foams with different structural variables have a spectrum characterization that influences the phase separation and topography of polyurethane foam areas because their bonding capability with hydrogen depends on chain extender nature. These studies may aid in shock absorption production; a methodology of elaboration and characterization of filled polyurethane foams is proposed.
Based on the models already on the market, we have manufactured six types of nonlethal projectiles. We have made convex heads out of polyurethane foam (PUR) filled with mineral fillers like alumina (Al2O3) and montmorillonite (MMT). We chose a suitable holder for nonlethal projectiles. Also, we made a custom industrial model and used CAD modeling in SolidWorks to simulate the deformation of the nonlethal projectiles. The polymeric nonlethal projectile holders were then 3D-printed. We performed a dynamic mechanical analysis (DMA) and discussed the results. Likewise, we conducted ballistic impact experiments on nonlethal projectiles (XM1006) and nonlethal projectiles manufactured that were evaluated using a rigid wall and a pneumatic launcher. Furthermore, we looked at cell structure, the spread of the mean pore diameter, and the particle size distributions of the mineral fillers using scanning electron microscopy (SEM). We evaluated and discussed injury risks from nonlethal impacts. Data on nonlethal projectile lethality and safe impact speed are collected. This study explains how lab studies and real-world practice coexist through nonlethal projectile properties.
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