Tephrochronology (from tephra, Gk "ashes") is a unique stratigraphic method for linking, dating, and synchronizing geological, palaeoenvironmental, or archaeological sequences or events. As well as utilizing the Law of Superposition, tephrochronology in practise requires tephra deposits to be characterized (or "fingerprinted") using physical properties evident in the field together with those obtained from laboratory analyses. Such analyses include mineralogical examination (petrography) or geochemical analysis of glass shards or crystals using an electron microprobe or other analytical tools including laser-ablation-based mass spectrometry or the ion microprobe. The palaeoenvironmental or archaeological context in which a tephra occurs may also be useful for correlational purposes. Tephrochronology provides greatest utility when a numerical age obtained for a tephra or cryptotephra is transferrable from one site to another using stratigraphy and by comparing and matching inherent compositional features of the deposits with a high degree of likelihood. Used this way, tephrochronology is an age-equivalent dating method that provides an exceptionally precise volcanic-event stratigraphy. Such age transfers are valid because the primary tephra deposits from an eruption essentially have the same short-lived age everywhere they occur, forming isochrons very soon after the eruption (normally within a year).As well as providing isochrons for palaeoenvironmental and archaeological reconstructions, tephras through their geochemical analysis allow insight into volcanic and magmatic processes, and provide a comprehensive record of explosive volcanism and recurrence rates in the Quaternary (or earlier) that can be used to establish time-space relationships of relevance to volcanic hazard analysis.The basis and application of tephrochronology as a central stratigraphic and geochronological tool for Quaternary studies are presented and discussed in this review. Topics covered include principles of tephrochronology, defining isochrons, tephra nomenclature, mapping and correlating tephras from proximal to distal locations at metre-through to sub-3 millimetre-scale, cryptotephras, mineralogical and geochemical fingerprinting methods, numerical and statistical correlation techniques, and developments and applications in dating including the use of flexible depositional age-modelling techniques based on Bayesian statistics.Along with reference to wide-ranging examples and the identification of important recent advances in tephrochronology, such as the development of new geoanalytical approaches that enable individual small glass shards to be analysed near-routinely for major, trace, and rare-earth elements, potential problems such as miscorrelation, erroneous-age transfer, and tephra reworking and taphonomy (especially relating to cryptotephras) are also examined. Some of the challenges for future tephrochronological studies include refining geochemical analytical methods further, improving understanding of cryptotephra dis...

NZ-INTIMATE members. 2007. Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ-INTIMATE project).

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Tephras are important for the NZ-INTIMATE project because they link all three records comprising the composite inter-regional stratotype developed for the New Zealand climate event stratigraphy (NZ-CES). Here we firstly report new calendar ages for 24 widespread marker tephras erupted since 30,000 calendar (cal.) years ago in New Zealand to help facilitate their use as chronostratigraphic dating tools for the NZ-CES and for other palaeoenvironmental and geological applications. The selected tephras comprise 12 rhyolitic tephras from Taupo, nine rhyolitic tephras from Okataina, one peralkaline rhyolitic tephra from Tuhua, and one andesitic tephra each from Tongariro and Egmont/Taranaki volcanic centres. Age models for the tephras were obtained using three methods: (i) 14 C-based wigglematch dating of wood from trees killed by volcanic eruptions (these dates published previously); (ii) flexible depositional modelling of a high-resolution 14 C-dated agedepth sequence at Kaipo bog using two Bayesian-based modelling programs, Bacon and OxCal's P_Sequence function, and the IntCal09 data set (with SH offset correction -44 ± 17 yr); and (iii) calibration of 14 C ages using OxCal's Tau_Boundary function and the SHCal04 and IntCal09 data sets. Our preferred dates or calibrated ages for the 24 tephras are as follows (youngest to oldest, all mid-point or mean ages of 95% probability ranges): Kaharoa AD 1314 ± 12; Taupo (Unit Y) AD 232 ± 10; Mapara (Unit X) 2059 ± 118 cal. yr BP; Whakaipo (Unit V) 2800 ± 60 cal. yr BP; Waimihia (Unit S) 3401 ± 108 cal. yr BP, Stent (Unit Q) 4322 ± 112 cal. yr BP; Unit K 5111 ± 210 cal. yr BP; Whakatane 5526 ± 145 cal. yr BP; Tuhua 6577 ± 547 cal. yr BP; Mamaku 7940 ± 257 cal. yr BP; Rotoma 9423 ± 120 cal. yr BP; Opepe (Unit E) 9991 ± 160 cal. yr BP; Poronui (Unit C) 11,170 ± 115 cal. yr BP; Karapiti (Unit B) 11,460 ± 172 cal. yr BP; Okupata 11,767 ± 192 cal. yr BP; Konini (bed b) 11,880 ± 183 cal. yr BP; Waiohau 14,009 ± 155 cal. yr BP; Rotorua 15,635 ± 412 cal. yr BP; 4 Rerewhakaaitu 17,496 ± 462 cal. yr BP; Okareka 21,858 ± 290 cal. yr BP; Te Rere 25,171 ± 964 cal. yr BP; Kawakawa/Oruanui 25,358 ± 162 cal. yr BP; Poihipi 28,446 ± 670 cal. yr BP; and Okaia 28,621 ± 1428 cal. yr BP.

a b s t r a c tThe Kawakawa/Oruanui tephra (KOT) is a key chronostratigraphic marker in terrestrial and marine deposits of the New Zealand (NZ) sector of the southwest Pacific. Erupted early during the Last Glacial Maximum (LGM), the wide distribution of the KOT enables inter-regional alignment of proxy records and facilitates comparison between NZ climatic variations and those from well-dated records elsewhere. We present 22 new radiocarbon ages for the KOT from sites and materials considered optimal for dating, and apply Bayesian statistical methods via OxCal4.1.7 that incorporate stratigraphic information to develop a new age probability model for KOT. The revised calibrated age, AE2 standard deviations, for the eruption of the KOT is 25,360 AE 160 cal yr BP. The age revision provides a basis for refining marine reservoir ages for the LGM in the southwest Pacific.Published by Elsevier Ltd.

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The discovery that orbital variations are the driving force behind Quaternary climate change provides an impetus to set local and regional records of environmental change into the global context, a principle that has been strongly embraced by Quaternary scientists working in New Zealand. Their major achievements and significant current initiatives are reviewed here. The importance of the New Zealand Quaternary stems from its geographical context: a climatically sensitive, remote oceanic, southern location spanning 17 degrees of the mid-latitudes; an obliquely convergent plate boundary setting resulting in a high mountain range athwart the prevailing westerlies, active volcanism, a youthful and dynamic landscape, and mountains high enough to maintain glaciers today; and a remarkably short prehistory. The resultant records show marked environmental changes due not only to climatic oscillations but also to vigorous, active tectonism and volcanism. The Taupo Volcanic Zone, containing the world's strongest concentration of youthful rhyolitic volcanoes, has produced at least 10 000 km3 of magma in the last 2 Ma. Climatic interpretations of records from marine sediments in the New Zealand region, together with several long sequences of alternating marine and terrestrial sediments, indicate broad synchrony with Northern Hemisphere events (within limitations of dating), although there are differences in detail for shorter-term climatic events. It is not yet certain that glacial advances coincided precisely with those in the Northern Hemisphere or were of similar duration. Late Cainozoic glaciation commenced c. 2.6-2.4 Ma but the record of glacial deposits is fragmentary and poorly dated except for the most recent events. The Last (Otira) Glaciation, from c. 100-10 ka, was characterized by at least five glacial advances including during the Last Glacial Maximum from 25 to 15 ka, when snowlines fell by 600-800 m. New Zealand evidence for cooling during the Younger Dryas stade is equivocal whilst isotopic records from speleothems, and other data, indicate warmer and wetter conditions from 10-7 ka, broadly conforming with records from mid-latitude Northern Hemisphere locations. Future advances will require sampling at shorter timescales, improvements in the accuracy and precision of existing dating methods and the development of new ones, extension of palaeoecological techniques to cover the full potential of new Zealand's diverse biota, and a stronger emphasis on quantification of palaeoclimatic parameters.