An overview of one of the most successful conducting polymers, poly(3,4-ethylenedioxythiophene) (PEDT) and its derivatives, is presented, detailing its early development, the synthesis of numerous hybrid and derivative materials, along with a description of the broad array of properties accessible and a description of a set of the more prominent applications in which they can be utilized. Synthetic flexibility and facility is the key to the many new 3,4-ethylenedioxythiophene-(EDT-) based monomers, oligomers, and (co)polymers. These (co)polymers provide highly conducting and especially stable doped states, a range of optical properties with electronic bandgaps varying across the entire visible spectrum, and enhanced redox properties, making them useful for numerous electrochemical devices. Present and future applications for PEDT that are discussed include static charge dissipation films and electrode materials in solid electrolyte capacitors.
Polycarbonate together with the acrylonitrile/butadiene/styrene copolymers, and the polyamides constitute the leading groups of engineering thermoplastics; for polycarbonate in particular, continued dynamic growth is prophesized.The underlying reason for this lies not only in its outstanding combination of technical properties and excellent price/performance balance, but also in the chemical and physical potential inherent in the basic structure of polycarbonate. The following review demonstrates with examples how this potential can be used in the development of new polycarbonates through the incorporation of alternative monomers, changes in the linear structure, end group variation, addition of special additives, and blending. The main emphasis of this article lies in the development of polycarbonates resistant to high temperature, with a good balance of technologically valuable properties. For scientific and practical interests a new criterion is offered for polycarbonates having both high-temperatures stability and impact strength."One must not only make a discovery, but also realize that a discovery has been made. '' Hermann Schnell [l]
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