We present a detailed study on the rear contact formation of rear-surface-passivated silicon solar cells by full-area screen printing and alloying of aluminum pastes on the locally opened passivation layer. We demonstrate that applying conventional Al pastes exhibits two main problems: 1) high contact depths leading to an enlargement of the contact area and 2) low thicknesses of the Al-doped p + Si regions in the contact points resulting in poor electron shielding. We show that this inadequate contact formation can be directly linked to the deficiently low percentage of silicon that dissolves into the Al-Si melt during alloying. Thus, by intentionally adding silicon to the Al paste, we could significantly improve the contact geometry by reducing the contact depth and enlarging the Al-p + thickness in the contact points, enabling a simple industrially feasible way for the rear contact formation of silicon solar cells.Index Terms-Aluminum alloying, local back surface field, local emitter, silicon solar cells.
Present address: Arizona State University, School of Electrical, Computer and Energy Engineering, 551 E. Tyler Mall, Tempe, AZ 85287, USA.Reducing wafer thickness while increasing power conversion efficiency is the most effective way to reduce cost per Watt of a silicon photovoltaic module. Within the European project 20 percent efficiency on less than 100-mm-thick, industrially feasible crystalline silicon solar cells ("20plms"), we study the whole process chain for thin wafers, from wafering to module integration and life-cycle analysis. We investigate three different solar cell fabrication routes, categorized according to the temperature of the junction formation process and the wafer doping type: p-type silicon high temperature, n-type silicon high temperature and n-type silicon low temperature. For each route, an efficiency of 19.5% or greater is achieved on wafers less than 100 mm thick, with a maximum efficiency of 21.1% on an 80-mm-thick wafer. The n-type high temperature route is then transferred to a pilot production line, and a median solar cell efficiency of 20.0% is demonstrated on 100-mm-thick wafers.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.