Tropical peatlands cover over 25 Mha in Southeast Asia and are estimated to contain around 70 Gt of carbon. Peat swamp forest ecosystems are an important part of the region's natural resources supporting unique flora and fauna endemic to Southeast Asia. Over recent years, industrial plantation development on peatland, especially for oil palm cultivation, has created intense debate due to its potentially adverse social and environmental effects. The lack of objective up‐to‐date information on the extent of industrial plantations has complicated quantification of their regional and global environmental consequences, both in terms of loss of forest and biodiversity as well as increases in carbon emissions. Based on visual interpretation of high‐resolution (30 m) satellite images, we find that industrial plantations covered over 3.1 Mha (20%) of the peatlands of Peninsular Malaysia, Sumatra and Borneo in 2010, surpassing the area of Belgium and causing an annual carbon emission from peat decomposition of 230–310 Mt CO2e. The majority (62%) of the plantations were located on the island of Sumatra, and over two‐thirds (69%) of all industrial plantations were developed for oil palm cultivation, with the remainder mostly being Acacia plantations for paper pulp production. Historical analysis shows strong acceleration of plantation development in recent years: 70% of all industrial plantations have been established since 2000 and only 4% of the current plantation area existed in 1990. ‘Business‐as‐usual’ projections of future conversion rates, based on historical rates over the past two decades, indicate that 6–9 Mha of peatland in insular Southeast Asia may be converted to plantations by the year 2020, unless land use planning policies or markets for products change. This would increase the annual carbon emission to somewhere between 380 and 920 Mt CO2e by 2020 depending on water management practices and the extent of plantations.

Many climate change mitigation strategies rely on strong projected growth in biomass energy, supported by literature estimating high future bioenergy potential. However, expectations to 2050 are highly divergent. Examining the most widely cited studies finds that some assumptions in these models are inconsistent with the best available evidence. By identifying literature-supported, up-to-date assumptions for parameters including crop yields, land availability, and costs, we revise upper-end estimates of potential biomass availability from dedicated energy crops. Even allowing for the conversion of virtually all 'unused' grassland and savannah, we find that the maximum plausible limit to sustainable energy crop production in 2050 would be 40-110 EJ yr À1 . Combined with forestry, crop residues, and wastes, the maximum limit to long-term total biomass availability is 60-120 EJ yr À1 in primary energy. After accounting for current trends in bioenergy allocation and conversion losses, we estimate maximum potentials of 10-20 EJ yr À1 of biofuel, 20-40 EJ yr À1 of electricity, and 10-30 EJ yr À1 of heating in 2050. These findings suggest that many technical projections and aspirational goals for future bioenergy use could be difficult or impossible to achieve sustainably.

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An optical gas sensor device based on tetra-substituted porphyrin dye entrapped in sol±gel glass displays greatly improved signal strength (1400% at 295 K) on exposure to 4.4 ppm nitrogen dioxide (in N 2 ) gas compared to a multilayer Langmuir±Blodgett ®lm fabricated from the same porphyrin. Temporal response was found to be similar, but differences in the two deposition methods were observed in terms of signal strength and response/recovery times. This behaviour is explained in terms of the differing nature of the two ®lm types. A room temperature sensitivity of 176 ppb was measured and the response obeyed Langmuir adsorption kinetics.

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