[1] The Model for Ozone and Related Chemical Tracers, version 3 (MOZART-3), which represents the chemical and physical processes from the troposphere through the lower mesosphere, was used to evaluate the representation of long-lived tracers and ozone using three different meteorological fields. The meteorological fields are based on (1) the Whole Atmosphere Community Climate Model, version 1b (WACCM1b), (2) the European Centre for Medium-Range Weather Forecasts (ECMWF) operational analysis, and (3) a new reanalysis for year 2000 from ECMWF called EXP471. Model-derived tracers (methane, water vapor, and total inorganic nitrogen) and ozone are compared to data climatologies from satellites. Model mean age of air was also derived and compared to in situ CO 2 and SF 6 data. A detailed analysis of the chemical fields simulated by shows that even though the general features characterizing the three dynamical sets are rather similar, slight differences in winds and temperature can produce substantial differences in the calculated distributions of chemical tracers. The MOZART-3 simulations that use meteorological fields from WACCM1b and ECMWF EXP471 represented best the distribution of long-lived tracers and mean age of air in the stratosphere. There was a significant improvement using the ECMWF EXP471 reanalysis data product over the ECMWF operational data product. The effect of the quasi-biennial oscillation circulation on long-lived tracers and ozone is examined.

Upper stratospheric enhancements in NOx (NO and NO2) were observed at high northern latitudes from March through at least July of 2004. Multi‐satellite data analysis is used to examine the temporal evolution of the enhancements, to place them in historical context, and to investigate their origin. The enhancements were a factor of 4 higher than nominal at some locations, and are unprecedented in the northern hemisphere since at least 1985. They were accompanied by reductions in O3 of more than 60% in some cases. The analysis suggests that energetic particle precipitation led to substantial NOx production in the upper atmosphere beginning with the remarkable solar storms in late October 2003 and possibly persisting through January. Downward transport of the excess NOx, facilitated by unique meteorological conditions in 2004 that led to an unusually strong upper stratospheric vortex from late January through March, caused the enhancements.

[1] Measurements from several different satellite instruments are used to estimate effects of energetic particle precipitation (EPP) on NO x (NO + NO 2 ) in the Southern Hemisphere stratosphere from 1992 to 2005. The focus is the EPP Indirect Effect (IE), whereby NO x produced in the mesosphere or thermosphere via EPP (EPP-NO x ) descends to the stratosphere during the polar winter, where it can participate in catalytic ozone destruction. EPP-NO x entering the stratosphere is found to vary in magnitude from 0.1 to 2.6 gigamoles per year, with maximum values occurring in 1994 and 2003. The interannual variation correlates strongly with several measures of EPP activity, including auroral and medium energy electron hemispheric power, and satellite measurements of thermospheric NO. This represents the first estimation of EPP-NO x contributions to the stratospheric odd nitrogen budget using observations over an entire solar cycle. The results will be useful for evaluating and constraining global models to investigate coupling of the upper and lower atmosphere by the EPP IE, including any influences this might have on ozone trends and possibly on climate.

Abstract. Solar eruptions sometimes produce protons, which impact the Earth's atmosphere. These solar proton events (SPEs) generally last a few days and produce high energy particles that precipitate into the Earth's atmosphere. The protons cause ionization and dissociation processes that ultimately lead to an enhancement of odd-hydrogen and oddnitrogen in the polar cap regions (>60 • geomagnetic latitude). We have used the Whole Atmosphere Community Climate Model (WACCM3) to study the atmospheric impact of SPEs over the period . The very largest SPEs were found to be the most important and caused atmospheric effects that lasted several months after the events. We present the short-and medium-term (days to a few months) atmospheric influence of the four largest SPEs in the past 45 years (August 1972;October 1989; as computed by WACCM3 and observed by satellite instruments. Polar mesospheric NO x (NO+NO 2 ) increased by over 50 ppbv and mesospheric ozone decreased by over 30% during these very large SPEs. Changes in HNO 3 , N 2 O 5 , ClONO 2 , HOCl, and ClO were indirectly caused by the very large SPEs in October-November 2003, were simulated by WACCM3, and previously measured by Envisat Michelson Interferometer for Passive Atmospheric Sounding (MIPAS). WACCM3 output was also represented by sampling with the MIPAS averaging kernel for a more valid comparison. Although qualitatively similar, there are discrepancies between the model and measurement with WACCM3 predicted HNO 3 and ClONO 2 enhancements being smaller than measured and N 2 O 5 enhancements being larger than measured. The HOCl enhancements were fairly Correspondence to: C. H. Jackman (charles.h.jackman@nasa.gov) similar in amounts and temporal variation in WACCM3 and MIPAS. WACCM3 simulated ClO decreases below 50 km, whereas MIPAS mainly observed increases, a very perplexing difference. Upper stratospheric and lower mesospheric NO x increased by over 10 ppbv and was transported during polar night down to the middle stratosphere in several weeks past the SPE. The WACCM3 simulations confirmed the SH HALOE observations of enhanced NO x in September 2000 as a result of the July 2000 SPE and the NH SAGE II observations of enhanced NO 2 in March 1990 as a result of the October 1989 SPEs.

[1] We report a new parameterization of ionization in the Earth's atmosphere by isotropically precipitating monoenergetic (100 eV to 1 MeV) electrons. This new parameterization is the first one based on sophisticated firstprinciple models, and represents a significant improvement in accuracy, particularly for incident auroral and lower energies. Without previous need to interpolate over source energy and atmospheric range, the new parameterization provides an easier implementation with a robust fit of model calculations for a wide range of incident energies and atmospheric conditions. By decomposing any incident energy spectrum into contiguous monoenergetic components and then calculating and integrating their resulting ionization, our parameterization is a valuable tool that can be used in conjunction with global models to accurately quantify the impact from realistic precipitating electrons during space weather events.

Measurements from the Atmospheric Chemistry Experiment show pronounced downward transport of NOx (NO+NO2) to the Arctic stratosphere in Feb–Mar 2006. NOx mixing ratios in the upper stratosphere were 3–6 times larger than observed previously in either the Arctic or Antarctic, aside from the extraordinary winter of 2003–2004. There was only minimal geomagnetic activity in late 2005 and early 2006, however, suggesting that NOx produced via energetic particle precipitation was not significantly elevated. On the other hand, the Arctic polar vortex at stratopause altitudes in Feb 2006 was exceptionally strong, implying greater confinement of air in the polar night. Carbon monoxide data also indicate enhanced confined descent of air from the mesosphere. These results confirm that impacts of EPP on the atmosphere are modulated by meteorological conditions; this has implications for understanding interannual variability and trends in stratospheric NOx and ozone.

The January 2022 Hunga Tonga–Hunga Ha’apai eruption was one of the most explosive volcanic events of the modern era1,2, producing a vertical plume that peaked more than 50 km above the Earth3. The initial explosion and subsequent plume triggered atmospheric waves that propagated around the world multiple times4. A global-scale wave response of this magnitude from a single source has not previously been observed. Here we show the details of this response, using a comprehensive set of satellite and ground-based observations to quantify it from surface to ionosphere. A broad spectrum of waves was triggered by the initial explosion, including Lamb waves5,6 propagating at phase speeds of 318.2 ± 6 m s−1 at surface level and between 308 ± 5 to 319 ± 4 m s−1 in the stratosphere, and gravity waves7 propagating at 238 ± 3 to 269 ± 3 m s−1 in the stratosphere. Gravity waves at sub-ionospheric heights have not previously been observed propagating at this speed or over the whole Earth from a single source8,9. Latent heat release from the plume remained the most significant individual gravity wave source worldwide for more than 12 h, producing circular wavefronts visible across the Pacific basin in satellite observations. A single source dominating such a large region is also unique in the observational record. The Hunga Tonga eruption represents a key natural experiment in how the atmosphere responds to a sudden point-source-driven state change, which will be of use for improving weather and climate models.

No abstract