Fibers that harvest mechanical energy via the triboelectric effect are excellent candidates as power sources for wearable electronics and functional textiles. Thus far however, their fabrication remains complex, and exhibited performances are below the state-of-the-art of 2D planar configurations, making them impractical. Here, we demonstrate the scalable fabrication of micro-structured stretchable triboelectric fibers with efficiencies on par with planar systems. We use the thermal drawing process to fabricate advanced elastomer fibers that combine a micro-textured surface with the integration of several liquid metal electrodes. Such fibers exhibit high electrical outputs regardless of repeated large deformations, and can sustain strains up to 560%. They can also be woven into deformable machine-washable textiles with high electrical outputs up to 490 V, 175 nC. In addition to energy harvesting, we demonstrate self-powered breathing monitoring and gesture sensing capabilities, making this triboelectric fiber platform an exciting avenue for multi-functional wearable systems and smart textiles.
The design of advanced materials with coupled optical and mechanical properties is an important challenge in materials science; especially, the implementation of soft materials in optics has recently gained significant interest. Soft optical systems are particularly versatile in sensing, where large and repeated deformations require dynamically responsive materials. Here, stretchable step‐index optical fibers, which are capable of reversibly sustaining strains of up to 300% while guiding light, are demonstrated. A continuous and scalable melt‐flow process is used to coextrude two thermoplastic elastomers, thereby forming the fibers' high index core‐low index cladding structure. Deformation of the fibers through stretching, bending, and indentation induces detectable, predictable, reversible, and wavelength‐dependent changes in light transmission. Quantitative knowledge about the coupling of the fibers' mechanical and optical properties forms the basis for the design of fiber‐based sensors that are capable of reliably assessing extreme mechanical stimuli. The fibers utility in sensing scenarios is demonstrated in a knee brace for continuous knee motion tracking, a glove for control of a virtual hand model, and a tennis racket capable of locating ball impacts. Such devices can greatly improve quantitative assessment of human motion in rehabilitation, sports, and anywhere else where large deformations need to be monitored reliably.
A microscopic theory is used to analyze optical gain in InGaN∕GaN quantum wells (QW). Experimental data are obtained from Hakki–Paoli measurements on edge-emitting lasers for different carrier densities. The simulations are based on the solution of the quantum kinetic Maxwell–Bloch equations, including many-body effects and a self-consistent treatment of piezoelectric fields. The results confirm the validity of a QW gain description for this material system with a substantial inhomogeneous broadening due to structural variation. They also give an estimate of the nonradiative recombination rate.
Flexible pressure sensors offer a wide application range in health monitoring and human-machine interaction. However, their implementation in functional textiles and wearable electronics is limited because existing devices are usually small, 0D elements, and pressure localization is only achieved through arrays of numerous sensors. Fiber-based solutions are easier to integrate and electrically address, yet still suffer from limited performance and functionality. An asymmetric cross-sectional design of compressible multimaterial fibers is demonstrated for the detection, quantification, and localization of kPa-scale pressures over m 2 -size surfaces. The scalable thermal drawing technique is employed to coprocess polymer composite electrodes within a soft thermoplastic elastomer support into long fibers with customizable architectures. Thanks to advanced mechanical analysis, the fiber microstructure can be tailored to respond in a predictable and reversible fashion to different pressure ranges and locations. The functionalization of large, flexible surfaces with the 1D sensors is demonstrated by measuring pressures on a gymnastic mat for the monitoring of body position, posture, and motion.
We investigated the degradation of cleaved facets of (Al,In)GaN laser diodes in different atmospheres. We found that operation in water-free atmospheres with sufficient oxygen shows a slow degradation. Operation in atmospheres with water vapor causes a fast degradation and an oxidation on the facet. This deposition is a permanent damage to the laser diode. If the laser diode is operated in pure nitrogen, we find a thick deposition on the facet, which shows high absorption. This deposition can be removed by either high optical output powers or by operation in atmospheres with sufficient oxygen. We also explain the influence of these coatings to the degradation behavior and see these coatings as the reason for unstable kinks in the L–I characteristics during operation.
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