In this paper, the refractory properties of clay from Ozanagogo had been studied for possible utilization in refractory production. The clay had a specific gravity of 2.57, linear firing shrinkage of 1.01%, 2.14 g/cm 3 bulk density and porosity of 20.4%. A cold crushing strength of 17.48 MN/m 2 was obtained with modulus of rupture of 8.28 MN/m 2 . The thermal shock resistance exceeded 30 cycles and the refractoriness was 1750˚C. The sample was analysed for its chemical composition, and it was revealed that it contained 38.07% alumina (Al 2 O 3 ), 46.00% silica (SiO 2 ) and iron impurities (Fe 2 O 3 ) of 0.78%. The results generally showed that Ozanagogo clay could be used as a refractory material.

Balanites aegyptiaca has multiplicity of uses and almost every part of the plant is useful including its flowers, leaves, bark, root and fruit. In this study, oil from Desert date (Balanites aegyptiaca) kernel seed was extracted, analyzed and used in the formulation of soap and lotion. The physical parameters determined were oil content, specific gravity, refractive index and moisture content. These were found to be 45.32% ± 0.0026%, 0.90 ± 0.03, 1.45% and 0.114% ± 0.04%, respectively. The chemical parameters evaluated include saponification value (200.02 ± 0.12 mg KOH/g), acid value (2.14 ± 0.28 mg KOH/g), iodine value (104.39 ± 0.00 100/g), peroxide value (2.95 ± 0.00 mEq/kg) and free fatty acid (0.82% ± 0.01%). The oil quality assessments test indicates %FFA content of 0.84% and the fatty acids composition of the oil was evaluated using GC-MS as FAME; the oil contains about 47.52% unsaturated fatty acids. The seed kernel of Balanites aegyptiaca is a good source of vegetable oil. Soap formulated from the oil is considered a good soap based on the soap quality parameters determined. Lotion formulated has a good stability when subjected to lotion stability test.

In this study, Dijah-Monkin bentonite clay was modified with a cationic surfactant hexadecyltrimethylammonium bromide (HDTMA-Br) at the level of twice the cation exchange capacity (CEC). This process results in the development of hydrophobic organoclay with an improved adsorption capacity. The clay obtained from Zing LGA Taraba State, North-East Nigeria, was beneficiated and pulverised to a particle size of 125 µm. The modification was performed without acid activation to prevent damages to the clay’s crystal structure. The organoclay was characterised for chemical composition, functional groups, mineralogical and surface morphology using X-ray fluorescence (XRF), Fourier Transform Infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The XRD showed an increase in the basal spacing from 15.681Å to 17.758 Å, while the XRF revealed a 5.35% concentration of Br on the modified clay, indicating successful intercalation. The FTIR spectra also revealed the appearance of symmetric and asymmetric stretching bands at 2847.7cm-1 and 2914.8cm-1, respectively, as a consequence of the modification, resulting in more sites for adsorption.

In this study, activated carbon was developed from saw-dust by pyrolysis. The activated carbon was characterized for elemental composition, morphology and surface chemistry. The potential of the prepared activated carbon for the removal of methylene blue (MB) from aqueous solution was investigated. Batch adsorption experiments were conducted to evaluate the adsorption isotherm, kinetic and thermodynamic of MB onto saw-dust activated carbon. The MB removal efficiency was 99.2% and the Lamgmuir isothermal model having correlation coefficient (R 2) of 0.98 gave the best fit. The kinetics of MB adsorption onto activated carbon was described with the pseudo second order model indicates the dominance of chemisorption mechanism. Thermodynamic parameters showed that the adsorption of MB on saw dust activated carbon adsorbent was endothermic in nature and a non-spontaneous process. The activation energy of 34.7 kJ/mol further reveals that the adsorption process was chemisorption. Generally, the results suggest that the saw-dust activated carbon is a viable adsorbent for effective removal of MB from wastewater effluent contaminated with dye.

One of the most important useful and widely abundant industrial minerals in the world is the clay minerals. Their applications in various industries are dependent on their properties. In this study, the mineralogical and physico-chemical properties of RahinSho (RC), Major Porter (MP), Wereng camp (WC), Kwi (KC) and Naraguta (NC) clay deposits in Plateau State, Nigeria were investigated to evaluate their potentials for some industrial uses. The x-ray diffraction studies revealed the kaolins as the dominant clay minerals in all the samples. The non-clay minerals found were quartz and muscovite. The chemical analyses by x-ray fluorescence also indicated that the silica (SiO 2) values of the samples ranged from (41.20-62.26)% while the alumina (Al 2 O 3) range was (17.25-37.15)%. Some considerable amounts of impurities found were Fe 2 O 3 (0.43-27.52)%, TiO 2 (0.05-3.28)%, K 2 O (0.13-3.01)%. The oxides of Na, Ca and Mg were within acceptable limits in the clays for most purposes. The loss on ignition ranged from 4.30%-12.43%. The physical properties investigated were particle size distribution that contained heavy clay-size materials ranging from 67.88%-91.88%, plasticity index had range of values from 15.90%-33.68%, and drying and firing shrinkages were 1.10%-2.22% and 1.65%-4.49% respectively. All the samples attained a temperature of 1500˚C without fusion except Naraguta clay that fused at 1300˚C. At the temperature of 1200˚C, RC, MP and WC clays retained their natural colours of white and near-white respectively, while KC and NC clays changed colours from orange pink and light brown to moderate pink and moderate reddish brown respectively. These results compare very well with several clays elsewhere. Based on these characteristics, the clays were observed to be potentially suitable for the production of paints, tiles, ceramics, refractories, sanitary wares and clay bricks. Minimal processing will increase the potential of RC and MP to meet up with specification for paper, fertilizer and/or pharmaceutical uses.