“…9 Also, it is possible to directly homo-and copolymerize free carboxylic acid bearing vinyl monomers using ULIS as reported here. For this work we have synthesized many unimolecular ligand-initiator systems (ULIS), 6 three of which are presented here in Fig. 1, namely, SBLI, TALI and TDLI, with different ligand components by employing various synthetic protocols (see the experimental section in ESIw).…”