The application of ZIF-67 and its derivatives: adsorption, separation, electrochemistry and catalysts

Zhong, Guihao; Liu, Dingxin; Zhang, Jianyong

doi:10.1039/c7ta08268a

Cited by 481 publications

(230 citation statements)

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“…[3,36,37] All of them, ZIF-8, possessing nitrogen-containing ligands, has high porosity and thermal stability. [37,44,45] The above-mentioned MOFs have been widely used for gas adsorption, molecular separation, catalysis, batteries, supercapacitors, and so on. [41] MIL-125, an active photocatalyst, includes cyclic octamers of TiO 2 octahedra.…”

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Metal‐Organic Framework‐Derived Carbons for Battery Applications

Zheng

Jin

et al. 2018

Advanced Energy Materials

185

112

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batteries, sodium-selenium (Na-Se) batteries, Li-tellurium (Li-Te) batteries, and Na-S batteries) have their own distinctive applications due to their various characteristics. To explore new materials with high performance, large studies have been devoted to the development of nextgeneration batteries.Porous carbon (PC) materials possess many unique properties due to their large surface areas, high conductivity, large pore volumes, high thermal stability, and surface functionalities, [22][23][24] leading to their wide use in energy storage and conversion. Traditionally, PC can be obtained via various methods, such as the direct heat treatment of organic precursors, hard template or nanocast methods, and soft template methods. However, the production of PC from these methods cannot be scaled-up because of certain barriers (disordered structure with wide size distributions, complicated processes, etc.). [23,25,26] Metal-organic frameworks (MOFs) have drawn wide research interest as a novel class of porous materials that are crystalline materials consisting of metal ions and organic ligands. [4,21,[27][28][29][30][31] Since the report on the MOF-templated synthesis of PC in 2008, [32] a large number of studies have been reported on the use of MOFs as suitable precursors/templates for carbon synthesis. [22,26,[33][34][35] At present, a large number of studies indicate that zeolitic imidazolate framework-8 (ZIF-8), MOF-5, MIL-125 (Ti) (MIL = Materials of Institute Lavoisier), and ZIF-67 with excellent thermal stability and unique porous structures are the more commonly used MOF precursors (Scheme 1). [3,36,37] All of them, ZIF-8, possessing nitrogen-containing ligands, has high porosity and thermal stability. [38][39][40] MOF-5 possesses excellent thermal stability, high porosity, and so on. [41] MIL-125, an active photocatalyst, includes cyclic octamers of TiO 2 octahedra. [42,43] ZIF-67 has a tunable pore aperture, highly stable structure, and catalytic activity. [37,44,45] The above-mentioned MOFs have been widely used for gas adsorption, molecular separation, catalysis, batteries, supercapacitors, and so on. [13,14,33] Moreover, carbon hybrids containing nanostructured metal species (e.g., metal oxides (MOs)) are likely to form under in situ carbonization conditions. [46] Compared with the carbonaceous materials from conventional precursors, MOF-derived carbon materials have significant advantages with high specific surface areas, tailorable porosities, unique morphologies, and easy functionalization with other heteroatoms. [14,23,31] For example, Xu and co-workers [47] obtained 1D carbon nanorods via the pyrolysis The applications of carbon and carbon-based materials with high porosity, high surface area, and functionalities based on metal-organic framework precursors and/or templates have attracted significant research interest in recent years, particularly in the field of batteries. The chemical and physical properties of carbon and carbon-based materials obtained by the heat treatment of various metal-organic ...

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confidence: 99%

“…[38][39][40] MOF-5 possesses excellent thermal stability, high porosity, and so on. [37,44,45] The above-mentioned MOFs have been widely used for gas adsorption, molecular separation, catalysis, batteries, supercapacitors, and so on. [42,43] ZIF-67 has a tunable pore aperture, highly stable structure, and catalytic activity.…”

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confidence: 99%

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Zheng

Jin

et al. 2018

Advanced Energy Materials

185

112

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“…Due to the presence of a large number of cobalt cations intrinsically mono‐dispersed in ZIF‐67, numerous cobalt based materials such as mono or bi‐metallic oxides/hydroxides/phosphides/selenides/sulfides with hollow, porous nanostructures can be fabricated directly from ZIF‐67 by using solvothermal and chemical vapor deposition (CVD) protocols. In addition, ZIF‐67 offers the ability to design plenty of bimetallic electrocatalysts or composites with nickel, iron, molybdenum, etc., from ZIF‐67 hybrids . These target structures are highly favorable for achieving enhanced electrochemical performance.…”

Section: Energy Conversion and Storagementioning

confidence: 99%

Electrochemical Energy Conversion and Storage with Zeolitic Imidazolate Framework Derived Materials: A Perspective

et al. 2018

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The development of transition‐metal‐based materials for electrochemical energy conversion and storage has received immense interest throughout the last two decades. In this respect, zeolitic imidazolate framework (ZIF)‐derived materials are particularly important for accessing various morphologies, sizes, exposed facets, variations in the electronic structure, high surface area, and large numbers of available active sites. The properties of the ZIF‐derived materials can be tuned by applying different synthetic protocols, introducing a heteroatom in the ZIF structure or by accessing core‐shell or hollow structures. Many studies have described the beneficial effects of ZIF‐derived materials, but no critical review is available in the growing field of electrochemical energy conversion and storage. Herein, we have described the basic principles of material synthesis from ZIFs, their applications in electrochemical processes, difficulties with the synthesis, and their future development.

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“…They are considered “zeolitic” due to their metal‐imidazole‐metal angle and topologies similar to zeolites . Among the various ZIFs, ZIF‐8 (Zn) and ZIF‐67(Co) have attracted extensive research interest because of its simple synthesis and various formulations, its outstanding thermal and chemical stability,, and various potential applications such as in catalysis and gas separation…”

Section: Figurementioning

confidence: 99%

Study of the Capacitive Behavior of MOF‐Derived Nanocarbon Polyhedra

et al. 2018

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Co containing zeolitic imidazolate framework (ZIF‐67) with polyhedral morphology was synthesized in aqueous media and utilized as precurser for synthesis of nanoporous carbon polyhedra without using any other carbon source. The phase, composition and morphology of the annealed products could be tailored by changing the annealing temperature as well as acid treatment. Our study herein provides a new insight into the formation of porous carbon polyhedra from ZIF‐67.

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The application of ZIF-67 and its derivatives: adsorption, separation, electrochemistry and catalysts

Abstract: This review explores the features and corresponding application of ZIF-67 and its derivatives.

Cited by 481 publications

References 65 publications

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Electrochemical Energy Conversion and Storage with Zeolitic Imidazolate Framework Derived Materials: A Perspective

Study of the Capacitive Behavior of MOF‐Derived Nanocarbon Polyhedra

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