Synthesis and evaluation of some amine compounds having surface active properties as H2S scavenger

Abstract

In this work three H 2 S scavengers were prepared by reacting monoethanolamine with formaldehyde in different ratios (1:1, 2:1 and 2:3) to give MF1, MF2 and MF3, respectively. The chemical structures of the prepared scavengers were confirmed by FT-IR spectroscopy. The effect of reaction time (the time required for completing the reaction between the scavenger and the H 2 S gas) has been studied for the three prepared scavengers. The effects of concentration and temperature have been studied on the scavenging efficiency of H 2 S using three prepared products and two commercial products EPRI-710 and EPRI-730. The surface and thermodynamic parameters of the prepared scavengers were determined at 25°C including, surface tension (c), and effectiveness, maximum surface excess (C max ) and minimum surface area (A min ). Also, the standard free energy of micellization and adsorption was recorded. The results show that the efficiency of scavengers increased with increasing reaction time up to 50 min. Also, as concentration of scavengers and temperature increased, the removal efficiency of the scavengers increased. By comparing the efficiency of the prepared products with the commercial products EPRI-710 and EPRI 730, it was found that, MF3 exhibited a similar efficiency comparing with the commercial scavenger EPRI 730 (currently used in the field) at different concentrations and temperatures. ª 2014 Production and hosting by Elsevier B.V. on behalf of Egyptian Petroleum Research Institute.

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“…Bending vibration of C-H, d(C-H) at 1381 cm −1 (Huang et al, 2013). Stretching vibration of C-O group, v(C-O) at 1097 cm −1 (Kandile et al, 2014).…”

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A Comprehensive Review of H2S Scavenger Technologies from Oil and Gas Streams

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