“…This is due to variations in both the ablation and laser plasma interaction processes, resulting also in possible variations of plume expansion in the background gas. As a result, different excitation and ionization levels of plasma species are achieved (Anzano, Villoria, Ruíz-Medina, & Lasheras, 2006;Krasniker, Bulatov, & Schechter, 2001). This signal feature makes it difficult to find the appropriate calibration standards for the LIBS methods.…”