Abstract:Effluent containing colour/dyes, especially reactive dyes, becomes a great concern of wastewater treatment because it is toxic to human life and aquatic life. In this study, reactive dye of Black B was separated using the supported liquid membrane process. Commercial polypropylene membrane was used as a support of the kerosene-tridodecylamine liquid membrane. Several parameters were tested and the result showed that almost 100% of 70 ppm Black B was removed and 99% of 70 ppm Black B was recovered at pH 2 of th… Show more
“…Removal and recovery mechanism of chromium ion by TOMAC a) The carrier, TOMAC in the membrane phase react with the stripping agent, NaOH at the membrane-internal interface as represented in Equation (5) . Therefore, at the feed-membrane interface, hydrochromate ions chemically react with both types of carrier as shown in Equation (6) and (7) (7) c) The formation of R 4 N-HCrO 4 complex diffuse across the membrane phase from feed-membrane interface to the membrane-internal interface reversibly, where the stripping reaction take place with stripping agent, NaOH as shown in Equation (8). The created complex HCrO 4 Na is insoluble in the membrane phase and will not diffuse back to the feed phase.…”
Section: Results and Discussion Mechanism Of Chromium Ions Transport mentioning
confidence: 99%
“…Liquid membrane technology has attracted much interest for its potential impact in the fields of separation processes because the main advantage of liquid membrane configuration treatment is a single step process, in which removal and recovery processes occur simultaneously [6,7]. This technique also provides high efficiency in separation and selectivity toward the desired solute as reported by Harrudin et al [8]. Liquid membrane technologies have been commonly used to separate and recover many types of metals from diluted solutions.…”
The presence of chromium in the natural water can be toxic to aquatic organism and is one of the major environmental problems. Therefore, the removal and recovery of chromium from industrial wastewater is very crucial to accomplish the standard discharge concentration limit. Supported liquid membrane is one of the processes which combines the extraction and recovery process in one single stage. This paper presents an experimental study on the removal and recovery of chromium ions from acidic aqueous solutions through a flat-sheet supported liquid membrane (FSSLM) system. Through this system, chromium ions were transported from feed phase into stripping phase via Tri-n-octyl-methylammoniumchloride (TOMAC)-kerosenepolypropylene supported liquid membrane (SLM). The liquid membrane phase was prepared by dissolving the corresponding volume of the carrier, TOMAC in organic diluent of kerosene. The stripping agent used was sodium hydroxide (NaOH) solution whereas the membrane support used was commercial Accurel polypropylene membrane with good features of 100 µm thickness, porosity of 72% and effective pore size of 0.10 µm. The chromium ion concentration in the feed and stripping phases as a function of time was analysed using an atomic absorption spectrometry (AAS). The effects of different operational variables such as TOMAC concentration in the membrane phase, NaOH concentration in the stripping phase and pH of the aqueous feed phase were investigated. The result demonstrated that about 90 and 98% of 150 ppm of chromium was removed and recovered, respectively at favorable condition of 1.0 M TOMAC, 0.5 M NaOH and pH 2 of the feed phase.Keywords: supported liquid membrane, chromium, removal, recovery, acidic aqueous solution Abstrak Kehadiran kromium di dalam sumber air semula jadi adalah toksik kepada organisma akuatik dan salah satu masalah utama alam sekitar. Oleh itu, penyingkiran dan pemulihan semula kromium daripada air sisa industri adalah sangat perlu untuk memenuhi had kepekatan piawaian pelepasan. Membran cecair berpenyokong adalah salah satu proses yang menggabungkan penyingkiran dan pemulihan semula dalam satu peringkat proses. Kertas kerja ini membentangkan satu kajian eksperimen tentang penyingkiran dan pemulihan semula ion kromium dari larutan berasid melalui sistem helaian rata membran cecair berpenyokong (FSSLM). Melalui sistem ini, ion kromium dibawa dari fasa suapan ke fasa pelucutan melalui Tri-n-oktil-metilammonium klorida (TOMAC)-kerosin-polipropilena membran cecair berpenyokong (SLM). Fasa cecair membran telah disediakan dengan melarutkan sejumlah pembawa, TOMAC dalam pelarut organik kerosin. Ejen pelucutan yang digunakan adalah larutan sodium hidroksida (NaOH) manakala membran sokongan yang digunakan ialah Accurel polipropilena membran komersial yang mempunyai ciri-ciri yang baik dengan ketebalan 100µm, keliangan 72% dan saiz liang 0.10 µm. Kepekatan ion kromium dalam
ISSN
-2506Raja Norimie & Norasikin: REMOVAL AND RECOVERY OF CHROMIUM(VI) ION VIA TRI-N-OCTYL METHYLAMMONIUMCHLORIDE-KERO...
“…Removal and recovery mechanism of chromium ion by TOMAC a) The carrier, TOMAC in the membrane phase react with the stripping agent, NaOH at the membrane-internal interface as represented in Equation (5) . Therefore, at the feed-membrane interface, hydrochromate ions chemically react with both types of carrier as shown in Equation (6) and (7) (7) c) The formation of R 4 N-HCrO 4 complex diffuse across the membrane phase from feed-membrane interface to the membrane-internal interface reversibly, where the stripping reaction take place with stripping agent, NaOH as shown in Equation (8). The created complex HCrO 4 Na is insoluble in the membrane phase and will not diffuse back to the feed phase.…”
Section: Results and Discussion Mechanism Of Chromium Ions Transport mentioning
confidence: 99%
“…Liquid membrane technology has attracted much interest for its potential impact in the fields of separation processes because the main advantage of liquid membrane configuration treatment is a single step process, in which removal and recovery processes occur simultaneously [6,7]. This technique also provides high efficiency in separation and selectivity toward the desired solute as reported by Harrudin et al [8]. Liquid membrane technologies have been commonly used to separate and recover many types of metals from diluted solutions.…”
The presence of chromium in the natural water can be toxic to aquatic organism and is one of the major environmental problems. Therefore, the removal and recovery of chromium from industrial wastewater is very crucial to accomplish the standard discharge concentration limit. Supported liquid membrane is one of the processes which combines the extraction and recovery process in one single stage. This paper presents an experimental study on the removal and recovery of chromium ions from acidic aqueous solutions through a flat-sheet supported liquid membrane (FSSLM) system. Through this system, chromium ions were transported from feed phase into stripping phase via Tri-n-octyl-methylammoniumchloride (TOMAC)-kerosenepolypropylene supported liquid membrane (SLM). The liquid membrane phase was prepared by dissolving the corresponding volume of the carrier, TOMAC in organic diluent of kerosene. The stripping agent used was sodium hydroxide (NaOH) solution whereas the membrane support used was commercial Accurel polypropylene membrane with good features of 100 µm thickness, porosity of 72% and effective pore size of 0.10 µm. The chromium ion concentration in the feed and stripping phases as a function of time was analysed using an atomic absorption spectrometry (AAS). The effects of different operational variables such as TOMAC concentration in the membrane phase, NaOH concentration in the stripping phase and pH of the aqueous feed phase were investigated. The result demonstrated that about 90 and 98% of 150 ppm of chromium was removed and recovered, respectively at favorable condition of 1.0 M TOMAC, 0.5 M NaOH and pH 2 of the feed phase.Keywords: supported liquid membrane, chromium, removal, recovery, acidic aqueous solution Abstrak Kehadiran kromium di dalam sumber air semula jadi adalah toksik kepada organisma akuatik dan salah satu masalah utama alam sekitar. Oleh itu, penyingkiran dan pemulihan semula kromium daripada air sisa industri adalah sangat perlu untuk memenuhi had kepekatan piawaian pelepasan. Membran cecair berpenyokong adalah salah satu proses yang menggabungkan penyingkiran dan pemulihan semula dalam satu peringkat proses. Kertas kerja ini membentangkan satu kajian eksperimen tentang penyingkiran dan pemulihan semula ion kromium dari larutan berasid melalui sistem helaian rata membran cecair berpenyokong (FSSLM). Melalui sistem ini, ion kromium dibawa dari fasa suapan ke fasa pelucutan melalui Tri-n-oktil-metilammonium klorida (TOMAC)-kerosin-polipropilena membran cecair berpenyokong (SLM). Fasa cecair membran telah disediakan dengan melarutkan sejumlah pembawa, TOMAC dalam pelarut organik kerosin. Ejen pelucutan yang digunakan adalah larutan sodium hidroksida (NaOH) manakala membran sokongan yang digunakan ialah Accurel polipropilena membran komersial yang mempunyai ciri-ciri yang baik dengan ketebalan 100µm, keliangan 72% dan saiz liang 0.10 µm. Kepekatan ion kromium dalam
ISSN
-2506Raja Norimie & Norasikin: REMOVAL AND RECOVERY OF CHROMIUM(VI) ION VIA TRI-N-OCTYL METHYLAMMONIUMCHLORIDE-KERO...
“…Afterwards, the acceptor phase is introduced into the analytical instrument of choice for the analysis. Examples of the use of SLME as an ecofriendly extraction technique include determination of metals in waste water [220], pesticides in water [221], phenols in water samples [222], black B dye in waste water [223] and basic drugs in human plasma [224].…”
Preparing a sample for analysis is a crucial step of many analytical procedures. The goal of sample preparation is to provide a representative, homogenous sample that is free of interferences and compatible with the intended analytical method. Green approaches to sample preparation require that the consumption of hazardous organic solvents and energy be minimized or even eliminated in the analytical process. While no sample preparation is clearly the most environmentally friendly approach, complete elimination of this step is not always practical. In such cases, the extraction techniques which use low amounts of solvents or no solvents are considered ideal alternatives. This paper presents an overview of green extraction procedures and sample preparation methodologies, briefly introduces their theoretical principles, and describes the recent developments in food, pharmaceutical, environmental and bioanalytical chemistry applications.
“…Highest flow rate of 2.79 L/h used was able to improve the degree of glucose extraction significantly to the value of 47.22%. At high flow rate, the boundary layer thickness between the feed and membrane can be reduced and hence promote better mass transfer [26,27].…”
Section: Effect Of Flow Rate On Glucose Extractionmentioning
Sugar is released during biomass hydrolysis together with unwanted inhibitory compounds such as acetic acid, furfural and hydromethylfurfural. The extraction of particular sugar prior to fermentation process is needed in order to increase the yield of biofuel generated from biomass resources. In the current study, glucose was extracted from the aqueous solution using supported liquid membrane (SLM) system. Polyethersulfone (PES) flat sheet membrane support was fabricated using 15 wt.% PES, 42.5 wt.% DMAc and 42.5 wt.% PEG 200. Liquid membrane was formulated using 2-ethyl hexanol and methyl cholate as solvent and carrier, respectively. The effect of several parameters involved in SLM system such as type of diluent and flowrate of feed and stripping phase on the extraction performance of glucose were studied. About 52.77% of glucose was successfully extracted from aqueous solution using SLM system with 0.01M of methyl cholate in 2-ethyl hexanol. Using simulated biomass hydrolysate solution, almost 54.55% of glucose and 51.08% of xylose were successfully extracted using the SLM system.
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