Quantitative determination of nitroglycerin by capillary gas chromatography—electron capture detection

Janssens, J.; Selala, M. I.; Daelemans, F.; Andries, S.; Schepens, Paul

doi:10.1016/0731-7085(89)80175-x

Cited by 5 publications

(2 citation statements)

References 3 publications

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“…Significant amounts of the active metabolites 1,2-and 1,3-dinitroglycerine could be demonstrated 560 . A major problem in the analysis of 273 and its metabolites is due to adsorption of the nitro compounds on the glassware used during sample preparation or injection.…”

Section: F Nitratesmentioning

confidence: 92%

Analytical Aspects of Amino, Quaternary Ammonium, Nitro, Nitroso and Related Functional Groups

Zabicky

Bittner

2009

Patai's Chemistry of Functional Groups

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Section: F Nitratesmentioning

confidence: 92%

Analytical Aspects of Amino, Quaternary Ammonium, Nitro, Nitroso and Related Functional Groups

Zabicky

Bittner

2009

Patai's Chemistry of Functional Groups

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“…Gibbs energies, enthalpies and entropies also have known [9]. Gas Chromatography is instrument that mostly used for identified nitroglycerin and its Derivatives [10][11][12][13][14][15]. Gas chromatography also can be used to quantify all product of nitration of glycerol [16].…”

Section: Introductionmentioning

confidence: 99%

Kinetic Modelling of Nitration of Glycerol: Three Controlling Reactions Model

Astuti¹,

Supranto²,

Rochmadi³

et al. 2014

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In the present study, a kinetic model of nitration between glycerol and nitric acid was developed. The presented model describes three controlling reactions model used elementary reactions consisting of three reversible reactions. The model utilizes first order reaction according to each reactant. The nitration of glycerol was modelled by fitting the kinetic model with 6 parameters, the rate constant at an average temperature and the activation energy. The reaction rate is assumed to be governed by three reactions, i.e. the formation of MNG (mononitroglycerin), the formation of DNG (dinitroglycerin) and the formation of TNG (nitroglycerin). The aim of this work is compare two models: seven controlling reactions model and three controlling reactions model. Two models have the similar trend. The three controlling reactions model gives better fit than seven controlling reactions model. The accuracy of three controlling reactions model is higher. The advantage of the seven controlling reactions model is this model can predict all products of nitration. So this model can be used at preliminary design plant. Three controlling reactions model can be used at next step, as design of reactor.

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Simultaneous determination of nitroglycerin and its dinitrate metabolites by capillary gas chromatography with electron-capture detection

Jørgensen¹,

Andersen²,

Hansen

1992

Journal of Chromatography B: Biomedical Sciences and Applicatio

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Quantitative determination of nitroglycerin by capillary gas chromatography—electron capture detection

Cited by 5 publications

References 3 publications

Analytical Aspects of Amino, Quaternary Ammonium, Nitro, Nitroso and Related Functional Groups

Analytical Aspects of Amino, Quaternary Ammonium, Nitro, Nitroso and Related Functional Groups

Kinetic Modelling of Nitration of Glycerol: Three Controlling Reactions Model

Simultaneous determination of nitroglycerin and its dinitrate metabolites by capillary gas chromatography with electron-capture detection

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