The slow component of the output pulse of Semi-Insulating (SI) Gallium Arsenide (GaAs) particle detectors, which affects charge collection efficiency (cce), has been generally attributed to trapping/detrapping effects. However, most of the detectors analyzed in the literature can only be operated below the voltage v d necessary to extend the electric field all the way to the ohmic contact, making difficult to distinguish between the effect of the non-active part of the detector and that of trapping/detrapping. To do that, we have carefully analyzed the output signals of SI GaAs detectors, operated below and above v d and irradiated with 241Am a particles.When the detector is biased below v d the output signals are affected also by the non-active part of the detector itself, while, when the detector is operated above Vd , the output signals are only affected by trappingldetrapping of charge carriers. We found that trappingldetrapping is only relevant for the hole contribution to the signal. Trapping/detrapping effects are in agreement with the characteristics of deep levels present in the detectors as analyzed by means of PICTS (Photo Induced Current Transient Spectroscopy) and P-DLTS (Photo Deep Level Transient Spectroscopy).