Phosphorus-based materials for high-performance rechargeable batteries

Qin, Xinyu; Yan, Bingyi; Jia, Yu; Jin, Jie; Yao, Takeshi; Mu, Chao; Wang, Sicong; Xue, Huaiguo; Pang, Huan

doi:10.1039/c7qi00184c

Cited by 35 publications

(18 citation statements)

References 105 publications

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“…15,16 Importantly, ball milling can break up commercial red P into nanosized particles without involving thermal evaporation and generation of white P. Unfortunately, the overall performance of ball-milled red P is far from satisfactory, compared with red P prepared by the well-used vaporization method. [17][18][19][20][21] For example, Park and Sohn 20 found the cycling performance of ball-milled red P for LIBs was extremely poor and only 10% of the initial capacity was maintained over 30 cycles. Even adding structural stability agents, nearly 50% loss over 100 cycles was still observed with ball-milled P/C composites.…”

Section: The Bigger Picturementioning

confidence: 99%

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

Jiang

Niu

Zhu

et al. 2018

Chem

133

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Red phosphorus (P), which has a high theoretical specific capacity ($2,600 mA hr g À1), low cost, and commercial availability, has been severely limited by large volume variation and poor electrical conductivity for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). Here, we fabricate a self-standing P/CNTs@rGO hierarchical structure to effectively resolve the critical issues associated with red P. The self-standing P/CNTs@rGO electrode achieves an unprecedented capacity and thus represents an advanced step toward high-performance P-based anodes for LIBs and SIBs.

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Section: The Bigger Picturementioning

confidence: 99%

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

Jiang

Niu

Zhu

et al. 2018

Chem

133

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“…Several attempts were reported to mitigate the degradation of BP and to improve the overall cyclability, as for instance (i) the use of fluoroethylene carbonate (FEC) additive in the electrolyte to form a more stable SEI, (ii) an upper cut-off potential of 0.8V (vs Na + /Na) to enhance reversibility [12][13][14] or (iii) the use of large amounts of conductive carbon to buffer the volume expansion during cycling. The latter was mostly achieved by producing P/C nanocomposites from red phosphorus and carbon via https://mc04.manuscriptcentral.com/jes-ecs high energy ball milling, often alongside the direct phase transformation of red to black phosphorus [7,15,16]. The extent of the phase transformation depends on experimental parameters, such as the spheres/material ratio, rotation speed and milling time] [17].…”

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confidence: 99%

Towards Advanced Sodium-Ion Batteries: Green, Low-Cost and High-Capacity Anode Compartment Encompassing Phosphorus/Carbon Nanocomposite as the Active Material and Aluminum as the Current Collector

Quartarone

Eisenmann

Kuenzel

et al. 2020

J. Electrochem. Soc.

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Sodium-ion batteries (SIBs) are promising alternative to Lithium-ion batteries for massive stationary energy storage. To improve energy density, however, more performing active materials are needed. In order to allow sustainable scale-up, it is also mandatory to develop green products and processes. Herein, we report on anodes of phosphorus/carbon (P/C) nanocomposites prepared via High Energy Ball Milling (HEBM), a simple, powerful and easily scalable synthesis technique. The electrodes were prepared under oxygen-free atmosphere, using water as solvent, which enabled the use of aluminum (instead of copper) as current collector, implying significant cost reduction. The P/C nanocomposite obtained after 54 hours HEBM resulted in excellent cycling stability, delivering very high specific capacity (2200 mAh g -1 , C/20) and showing good capacity retention after 120 cycles. A careful structural analysis (XRD, FESEM-EDS, XPS), revealed that long milling times strongly increased cycling stability due to: i) significant decrease of P particle size inside the matrix and deep composite amorphization, which alleviates the buffering dimensional issues typical of black phosphorus; ii) presence of defects in the carbonaceous component, which allows easier Na + insertion into the anode. Our results show that P/C nanocomposites are very promising anode materials for SIBs, paving the way for further exploitation of nano-architectures in SIBs technology.

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“…Lithium-ion batteries (LIBs), as classic rechargeable battery systems, have become vital energy storage systems in our everyday lives since their commercialization. [1][2][3][4][5][6][7][8][9][10][11] However, LIBs cannot fully satisfy the rapidly growing market demand because the energy density that can be achieved with the current systems is approaching its limit. [12][13][14][15][16][17][18][19] Therefore, development of alternative advanced electrical energy storage devices that can provide high energy densities has become a research hotspot.…”

Section: Introductionmentioning

confidence: 99%

Metal–Organic Framework‐Based Sulfur‐Loaded Materials

Du¹,

Li²,

Zhang³

et al. 2021

Energy & Environ Materials

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Lithium‐sulfur batteries (LSBs) are considered promising new energy storage systems given their outstanding theoretical energy densities. Nevertheless, issues such as low electrical conductivity and severe volume expansion, along with the formation of polysulfides during cycling, restrict their practical applications. To overcome these issues, it is necessary to find suitable and effective sulfur host materials. Metal–organic frameworks (MOFs), which are porous crystalline materials in the bourgeoning developmental stages, have demonstrated enormous potential in LSBs owing to their high porosity and tunable porous structure. Herein, we provide a comprehensive overview of MOF‐based sulfur‐loaded materials and discuss the charge/discharge mechanisms, strategies of enhancing battery performance, sulfur loading methods, and applications in LSBs. An outlook on future directions, prospects, and possible obstacles for the development of these materials is also provided.

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Phosphorus-based materials for high-performance rechargeable batteries

Abstract: A review of P based materials used in LIB/NIB and their synthesis strategies, tailored materials properties and different electrochemical performances.

Cited by 35 publications

References 105 publications

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

Towards Advanced Sodium-Ion Batteries: Green, Low-Cost and High-Capacity Anode Compartment Encompassing Phosphorus/Carbon Nanocomposite as the Active Material and Aluminum as the Current Collector

Metal–Organic Framework‐Based Sulfur‐Loaded Materials

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