A novel technique of self-assembly and transfer of a photoresist thin film assisted by metallization is presented for planarization in microelectromechanical systems (MEMS) in this paper. The AZ5214 photoresist thin film was self-assembled on the water-gas interface and then the entire film was transferred to the wafer surface. The photoresist suspended over trenches to form a planar surface proved to be useful as a bridge layer for the subsequent processes in MEMS. Metal layers were then sputtered on the photoresist and patterned by dry etching. After sacrificially etching the photoresist bridge layer, metal beams and cantilevers were released and suspended over the trenches. It was found that the suspension capability of the AZ5214 photoresist thin film increased with the film thickness and a 300 nm thick photoresist was sufficient to span a 50 μm trench without breaking. Both 350 nm thick Cu double-clamped beams and cantilevers, suspended over trenches, were successfully prepared using the proposed method.