An organic nonlinear optical (NLO) crystal of ammonium p-toluenesulfonate (AMPTS) was grown by a slow evaporation solution growth technique. A single crystal X-ray diffraction study revealed that the AMPTS crystal belongs to orthorhombic system with the space group of Pna2 1 . From the UV-Vis-NIR spectral study, refractive index and extinction coefficient were determined. The nonlinear refractive index, nonlinear absorption coefficient and third-order NLO susceptibility were calculated to be -5.2872 9 10 -8 cm 2 /W, 7.035 9 10 -3 cm/W and 3.44 9 10 -6 esu, respectively, by Z-scan studies. The laser damage threshold of AMPTS crystal was found to be 4.08, 4.0 and 3.95 GW/cm 2 for (10-1), (-110) and (001) planes, respectively, using a Nd:YAG laser source. Etching study revealed the surface quality of AMPTS crystal.