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TiO 2 nanoparticles doped with different concentrations of cobalt (4, 8, 12 and 16 %) were synthesized by sol-gel method at room temperature with appropriate reactants. In general, TiO 2 can exist in anatase, rutile, and brookite phases. In this present study, we used titanium tetra iso propoxide and 2-propanol as a common starting materials and the obtained products were calcined at 500°C and 800°C to get anatase and rutile phases, respectively. The crystalline sizes of the doped and undoped TiO 2 nanoparticles were observed with X-ray diffraction (XRD) analysis. The functional groups of the samples were identified by Fourier transform infrared spectroscopy (FTIR). From UV-VIS diffuse reflectance spectra (DRS), the band gap energy and excitation wavelength of doped and undoped TiO 2 nanoparticles were identified. The defect oriented emissions were seen from photoluminescence (PL) study. The spherical uniform size distribution of particles and elements present in the samples was determined using two different techniques viz., scanning electron microscopy (SEM) with energy-dispersive spectrometer (EDX) and transmission electron microscope (TEM) with selected area electron diffraction (SAED) pattern. The second harmonic generation (SHG) efficiency was also found and the obtained result was compared with potassium di hydrogen phosphate (KDP).

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According to Vision 2030, the Kingdom of Saudi Arabia (K.S.A) plans to harness 9.5 GW of energy from renewable energy sources, which includes a major part of solar PV generation. This massive implementation of solar projects requires an accurate assessment and analysis of solar resource data and PV site selection. This paper presents a detailed analysis of one-year solar radiation data and energy output of 100 kW PV systems at 44 different locations across the K.S.A. Coastal areas have a lower amount of global horizontal irradiance (GHI) as compared to inland areas. Najran University station gives the highest annual electrical output of 172,083 kWh, yield factor of 1721, and capacity utilization factor of 19.6%. Sharurah and Timma TVTC are second and third best with respect to annual PV performance. Similarly, during high load summer season (April-October), Tabuk station is the best location for a PV power plant with an electrical output of 110,250 kWh, yield factor of 1102, and capacity utilization factor of 21.46%. Overall, the northern province of Tabuk is the most feasible region for a solar PV plant. The basic approach presented in this research study compares solar resource pattern and solar PV system output pattern with the load profile of the country. The site selected based on this criterion is recommended to be economically most feasible which can reduce the stress on electricity companies during high load seasons by clipping the peak load during daytime in the hot summer period.

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