2005
DOI: 10.1063/1.1864255
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Modification of GaAs Schottky diodes by thin organic interlayers

Abstract: Modification of GaAs Schottky diodes by thin organic interlayers, A.R. Vearey-Roberts and D.A. Evans, Appl. Phys. Lett. 86, 072105 (2005)Control of the interfacial potential barrier for metal/n-GaAs diodes has been achieved using thin interlayers of the organic semiconductor, tin phthalocyanine (SnPc). The I-V characteristics for organic-modified Ag/S:GaAs diodes indicate a change from rectifying to almost ohmic behavior as the thickness of the SnPc interlayer is increased. Modeling reveals thermionic emission… Show more

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Cited by 140 publications
(56 citation statements)
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References 15 publications
(35 reference statements)
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“…Gavrila et al [21] have reported a barrier enhancement of 0.3 eV with DiMePTCDI interlayers on S-GaAs(100). There are many other reports of PTCDI and PTCDA modifications on GaAs [11,[22][23][24].…”
Section: Introductionmentioning
confidence: 98%
“…Gavrila et al [21] have reported a barrier enhancement of 0.3 eV with DiMePTCDI interlayers on S-GaAs(100). There are many other reports of PTCDI and PTCDA modifications on GaAs [11,[22][23][24].…”
Section: Introductionmentioning
confidence: 98%
“…This indicates that the introduction of PANI interlayer influenced the interfacial potential barrier of the Ti/InP Schottky junction, resulting in a modification of the effective barrier height, as shown in Fig. 2 [6,23,24]. Namely, PANI interlayer can act as a physical barrier between Ti film and p-type InP substrate for preventing their direct contact, causing a substantial shift in the work function of a metal and in the electron affinity of a semiconductor.…”
Section: Resultsmentioning
confidence: 99%
“…According to Roberts and Evans, the change in the barrier height is attributed to the change in the inorganic substrate band bending due to interaction between the metal layer and the organic modified substrate. 28,29) Typical ideality factors determined by the effect of image force lowering are close to 1.01 or 1.02. 30,31) The higher ideality factor values in the Au/CuPc/n-GaN structure could be attributed to secondary mechanisms such as interfacial dipoles caused by the organic interlayer or a specific interface structure or even fabrication-induced interfacial defects.…”
Section: Resultsmentioning
confidence: 99%