IntroductionCatalysis has been closely associated to the development of our technological modern society for more than 100 years and continues to be so today [1] . The two fi rst worldwide examples of catalysis intervention were fi rst, the Fischer -Tropsch synthesis, allowing the transformation of coal into valuable liquid fuels, which provided an energetic power supply to the German army during World War II [2] , where the nine plants in operation have a combined capacity of about 660 × 10 3 t per year; the second concerns the improvement of the octane number, still during World War II, to improve the performance of the allied aircraft during the battle of Britain [3] . The British lost 915 planes compared to the 1733 lost by the Germans. This was because of their superior maneuverability with 50% faster bursts of acceleration from their 100 -octane fuel compared to the German 87 -octane fuel. Since then an exponential increase in the participation of catalytic processes has been observed in the development of the industrialised countries. A catalyst allows the transformation of reactants into desired products with high selectivity reducing at the same time the cost linked with waste disposal. Many types of materials can be used as catalysts. These include metals, compounds, i.e. metal oxides, sulfi des, carbides, nitrides, etc., organometallic complexes, and enzymes. Most of the industrially employed catalysts are dispersed on high surface area supports (alumina, silica or activated carbon) in order to increase the number of active sites.The application and development of an industrial catalyst starts with research and control of materials at the molecular level followed by laboratory evaluation and a microplant reactor which pave the way to the real industrial catalyst. All of these processes cover several domains of research, from molecular chemistry to transport phenomena and solid state studies. Today the understanding of the macroscopic phenomena involved in catalysis seems to be relatively well under control for most of the different catalytic processes whereas the comprehension of what happens at a nanoscopic scale remains to be improved, in order to design a new generation of catalysts with better activity and selectivity. The direct way to 219 Nanoparticles and Catalysis. Edited by Didier Astruc