“…The initial gaseous compounds for silicon are silane SiH 4 and silicon tetrafluoride SiF 4 , while for germanium there are germane GeH 4 , and, less often, germanium tetrafluoride GeF 4 [5,6] though the latter provides for the best photoelectric structure properties [2,7]. The capacitive discharge (110 kHz) PECVD with GeF 4 as the initial substance was also used to grow photosensitive layers of amorphous germanium a-Ge:F for fabrication of uncooled micro-bolometers showing good performance parameters [8,9]. Plasma-enhanced hydrogen reduction of GeF 4 in a RF (13.56 MHz) inductively-coupled discharge has been recently suggested for the production of stable germanium isotopes in form of layers and bulk samples [10].…”