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2006
DOI: 10.1007/s11664-006-0166-1
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Interfacial reaction between Sn-Bi alloy and Ni substrate

Abstract: Interfacial reactions between Sn-Bi alloys of different compositions and Ni substrates at 423 K for different durations were investigated. Only one interfacial phase, Ni 3 Sn 4 , was detected despite the existence of several other intermetallic compounds (IMCs) in Ni-Sn and Ni-Bi binary systems. This observation (only Ni 3 Sn 4 was formed at the interface) was explained as a combination of the driving force for formation of the IMC and diffusion of Ni. The change of Ni 3 Sn 4 layer thickness as a function of a… Show more

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Cited by 27 publications
(10 citation statements)
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“…The results obtained in this study were in accordance with the Sn-58Bi/Ni system. 18 The Ni layer remained in all the SB/Au/Ni/SUS304 couples, demonstrating that this layer acted as an excellent barrier between the solder and the substrate. Figure 2 shows the linear relationship between the IMC thickness and the square root of reaction time in all the SB/Au/Ni/SUS304 couples reacted at three reaction temperatures, for different reaction times.…”
Section: Resultsmentioning
confidence: 92%
“…The results obtained in this study were in accordance with the Sn-58Bi/Ni system. 18 The Ni layer remained in all the SB/Au/Ni/SUS304 couples, demonstrating that this layer acted as an excellent barrier between the solder and the substrate. Figure 2 shows the linear relationship between the IMC thickness and the square root of reaction time in all the SB/Au/Ni/SUS304 couples reacted at three reaction temperatures, for different reaction times.…”
Section: Resultsmentioning
confidence: 92%
“…According to Ref. [15], during liquid aging, Sn participated from solder matrices and reacted with Cu to form IMC phase, so that a composition gradient of Bi element formed against the interface in the molten solder. Therefore, fine Bi-rich particles formed in the solidification process after the liquid aging.…”
Section: Methodsmentioning
confidence: 99%
“…[3][4][5][6][7][8] Among them, Sn-Bi alloys are attractive as solder alloys due to their low melting temperature, low cost, and good mechanical properties, such as tensile strength and creep resistance, compared with Sn-Pb alloy. [9][10][11] In particular, Sn-58 wt.%Bi alloy with eutectic composition has low melting temperature of 138°C, showing that it is possible to reflow at low processing temperature. 12 Low-temperature soldering is necessary because electronic devices are prone to thermal damage during high-temperature reflow processing, which damages not only the solder joints but also the printed circuit board (PCB) and components.…”
Section: Introductionmentioning
confidence: 99%