2020
DOI: 10.1016/j.tsf.2019.137687
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Influence of two-dimensional oxide nanosheets seed layers on the growth of (100)BiFeO3 thin films synthesized by chemical solution deposition

Abstract: Highlights  Synthesis of BiFeO3 thin films by chemical solution deposition.  Randomly oriented growth of BiFeO3 films on silica and (100)Si.  Highly (100) oriented growth of BiFeO3 on Ca2Nb3O10-nanosheets seed layers.  Low cost processes at low temperature on inexpensive large area substrates.

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Cited by 7 publications
(6 citation statements)
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References 30 publications
(31 reference statements)
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“…NS are obtained by an exfoliation process of various layered oxides [31] and transferred by Langmuir-Blodgett (LB) method (Figure 1a,b) [32] on substrates that, when used bare, are non-adapted for complex oxide deposition, such as silicon or glass. The exceptionally rich structural diversity of NS makes them interesting growth templates for oxides [30,[33][34][35][36][37][38][39][40] or metals. [41] SVO has a cubic perovskite structure with a lattice parameter a = 0.384(1) nm [42] whereas CVO is orthorhombically (o) distorted with pseudo-cubic (pc) a pc = a o /√2 = b o /√2 = c o /2 ≈0.377(1) nm.…”
Section: Resultsmentioning
confidence: 99%
“…NS are obtained by an exfoliation process of various layered oxides [31] and transferred by Langmuir-Blodgett (LB) method (Figure 1a,b) [32] on substrates that, when used bare, are non-adapted for complex oxide deposition, such as silicon or glass. The exceptionally rich structural diversity of NS makes them interesting growth templates for oxides [30,[33][34][35][36][37][38][39][40] or metals. [41] SVO has a cubic perovskite structure with a lattice parameter a = 0.384(1) nm [42] whereas CVO is orthorhombically (o) distorted with pseudo-cubic (pc) a pc = a o /√2 = b o /√2 = c o /2 ≈0.377(1) nm.…”
Section: Resultsmentioning
confidence: 99%
“…Polycrystalline BFO with preferential (100) PC orientation has been obtained on (111) Pt by means of a chemical solution route [239]. More recently, nanosheets of Ca 2 Nb 3 O 10 have been successfully used as a seed layer for highly oriented (100) PC BFO grown on Si [240]. BiFeO 3 films directly deposited on metallic substrates have not been intensively investigated.…”
Section: Bifeomentioning
confidence: 99%
“…The PFM images represent switching behavior between perpendicular components of polarization, which can be divided into two states: dark and bright. The bright region corresponds with downward direction of polarization, which means that the polarization vector is oriented downward and associated with the [111] or [1][2][3][4][5][6][7][8][9][10][11] polarization direction [30]. Dark regions, on the other hand, are oriented upward and related [−1 -11] or [−111] direction [30].…”
Section: Piezoresponse Force Microscopy Analysismentioning
confidence: 99%
“…The angle α is around 60 degrees [1]. Aside from having the unique combination of a magnetic and ferroelectric response, the material shows outstanding temperature stability with a high Curie [2] (Tc = 1120 K) point. The bismuth ferrite has a complex magnetic structure [3] due to interaction between its magnetic and electric dipoles [4].…”
Section: Introductionmentioning
confidence: 99%