1983
DOI: 10.1021/j100228a021
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Hydrogen generation by photocatalytic oxidation of glucose by platinized n-titania powder

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Cited by 106 publications
(40 citation statements)
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“…[11] These UV light-absorbing photocatalysts achieved performances up to 1.15 mmol H 2 g cat À1 h À1 , [12] and 8.5 %E QE.…”
Section: Sugarsmentioning
confidence: 99%
See 1 more Smart Citation
“…[11] These UV light-absorbing photocatalysts achieved performances up to 1.15 mmol H 2 g cat À1 h À1 , [12] and 8.5 %E QE.…”
Section: Sugarsmentioning
confidence: 99%
“…PR in D 2 Oh as shown that the generated H 2 originates from the aqueous solvent rather than the biomass. [11,31] BOR is am ore complex multi-step process that directly involves the substrate.PRrates with various substrates differ depending on the substrates adsorption to the photocatalyst surface.…”
Section: The Pr Mechanismmentioning
confidence: 99%
“…The primary difference between the PR and the PCO is that the former was performed under aerobic conditions [32,39,44], but the latter under aerated conditions. Thus, the formation of O 2 •− was avoided.…”
Section: Tablementioning
confidence: 99%
“…Der geläufigste Photoktalysator zur PR von Glucose ist Pt/TiO 2 , [11] das ausschließlich UV-Licht absorbiert und dabei Aktivitäten bis zu 1.15 mmol H 2 g cat À1 h À1 [12] und 8.5 %E QE erreicht.…”
Section: Zuckerunclassified
“…Die HER ist substratunabhängig und läuft in der Regel an metallischen Cokatalysatoren wie Pt ab.D er Cokatalysator wirkt dabei gleichzeitig als Schottky-Barriere,d ie Rekombination verhindert, und als HER-Katalysator.PRinD 2 Ozeigt, dass der gebildete H 2 dem Lçsungsmittel Wasser entstammt und nicht aus der Biomasse gebildet wird. [11,31] Die BOR ist ein komplexerer,m ehrstufiger, substratabhängiger Prozess.U nterschiedliche Substrate zeigen verschiedene PR-Geschwindigkeiten, je nach ihrer Adsorption an der Oberfläche des Photokatalysators.…”
Section: Der Mechanismus Der Prunclassified